Structural evolution and kinetic study of high isotacticity poly(acrylonitrile) during isothermal pre-oxidation

Li Zhang; Yongqiang Dai; Yi Kai; Ri-guang Jin

Isotactic polyacrylonitrile (PAN) with triad isotacticity of 0.53, which was determined by 13C nuclear magnetic resonance, using dialkylmagnesium as an initiator, was successfully synthesized. Isothermal treatment of iso-PAN was conducted in air at 200, 220, 250 and 280oC. Structural evolutions and chemical changes were studied with Fourier transformation infrared and wide-angle X-ray diffraction during stabilization. A new parameter carbon nanofiber = I2240cm -1/ (I1595cm -1+f*I1595cm -1) was defined to evaluate residual nitrile groups. Crystallinity and crystal size were calculated with X-ray diffraction dates. The results indicated that the nitrile groups had partly converted into a ladder structure as stabilization proceeded. The rate of reaction increased with treatment temperature; crystallinity and crystal size decreased proportionally to pyrolysis temperature. The iso-conversional method coupled with the Kissinger and Flynn-Wall-Ozawa methods were used to determine kinetic parameters via differential scanning calorimetry analysis with different heating rates. The active energy of the reaction was 171.1 and 169.1 kJ/mol, calculated with the two methods respectively and implied the sensitivity of the reaction with temperature.

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* 2021년 이후 발행 논문의 참고문헌은 현재 구축 중입니다.

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