Preparation and characterization of RGO‑incorporated hypercross‑linked polymers for  CO2 capture

Rajangam Vinodh; Cadiam Mohan Babu; Aziz Abidov; Muthiah Pillai Palanichamy; Wang Seog Cha; Hyun Tae Jang

doi:10.1007/s42823-019-00002-6

The growing demand for nano-structured composite materials and sustainable processes for next generation CO2 capture technologies has necessitated the need to develop novel and cost-effective synthetic routes for solid CO2 adsorbents based on hypercross-linked polymers (HCPs) and reduced graphene oxide (RGO) microporous sorbent materials with improved physico-chemical properties. The most important selection is modification of the synthesized microporous sorbent materials by the incorporation of RGO, giving rise to composite materials that combine the properties of both. These hybrid materials will be of great potential for carbon capture and storage (CCS) applications, especially for post-combustion CO2 capture, owing to the increase in CO2 capturing efficiency and selectivity to CO2 compared to other flue gases. Herein, we report a facile and effective approach for fabrication of HCPs-supported reduced graphene oxide composites. The microporous HCPs was synthesized using 4,4′-bis(chloromethyl)-1,1′-biphenyl monomer by Friedel–Crafts alkylation. The RGO was prepared by modified Hammers method. The as-synthesized composites were characterized by TEM, SEM, FTIR, TGA and N2 adsorption–desorption isotherm. The HCP/RGO composite showed maximum CO2 adsorption of 5.1 wt% than the HCPs alone at 40 °C and 1 atm.

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REFERENCES (44)
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* 2021년 이후 발행 논문의 참고문헌은 현재 구축 중입니다.

[journal] Haszeldine RS / 2009 / Carbon capture and storage: how green can black be? / Science 325 : 1647~ / https://doi.org/10.1126/science.1172246

[journal] D’Alessandro DM / 2010 / Carbon dioxide capture : prospects for new materials / Angew Chem Int Ed 49 : 6058~ / https://doi.org/10.1002/anie.201000431

[journal] Wang W / 2017 / Carbon dioxide capture in amorphous porous organic polymers / J Mater Chem A 5 : 1334~ / https://doi.org/10.1039/C6TA09234A

[journal] Ziyan J / 2017 / High gas uptake and selectivity in hyper-crosslinked porous polymers knitted by various nitrogen-containing linkers / Chem Open 6 : 554~ / https://doi.org/10.1002/open.201700073

[journal] Sanz-Perez ES / 2016 / Direct capture of CO2from ambient air / Chem Rev 116 : 11840~ / https://doi.org/10.1021/acs.chemrev.6b00173

[journal] Wu ZK / 2016 / Kinetic analysis and regeneration performance of 1-butyl-3-methylimidazolium glycinate solutions for CO2capture / Chem Eng J 295 : 64~ / https://doi.org/10.1016/j.cej.2016.03.030

[journal] Wang TL / 2015 / Towards an understanding of the oxidative degradation pathways of AMP for post-combustion CO2capture / Int J Greenhouse Gas Control 37 : 354~ / https://doi.org/10.1016/j.ijggc.2015.03.017

[journal] Luo C / 2014 / Effect of sulfation on CO2capture of CaO-based sorbents during calcium looping cycle / Fuel 127 : 124~ / https://doi.org/10.1016/j.fuel.2013.09.063

[journal] Vinodh R / 2017 / Effect of Zr and Li on high temperature CO2sorption characteristics of CaO / Adsorption 23 : 1033~ / https://doi.org/10.1007/s10450-017-9915-0

[journal] Li CF / 2017 / Pyrene-cored covalent organic polymers by thiophene-based isomers, their gas adsorption, and photophysical properties / J Polym Sci Part A Polym Chem 55 : 2383~ / https://doi.org/10.1002/pola.28627

[journal] Chanda DK / 2017 / Nanoflower, nanoplatelet and nanocapsule Mg(OH)2 powders for adsorption of CO2gas / J Mater Sci 52 : 4910~ / https://doi.org/10.1007/s10853-016-0728-4

[journal] Wu DC / 2012 / Design and preparation of porous polymers / Chem Rev 112 : 3959~ / https://doi.org/10.1021/cr200440z

[journal] Ding SY / 2013 / Covalent organic frameworks(COFs) : from design to applications / Chem Soc Rev 42 : 548~ / https://doi.org/10.1039/C2CS35072F

[journal] Dawson R / 2011 / Microporous organic polymers for carbon dioxide capture / Energy Environ Sci 4 : 4239~ / https://doi.org/10.1039/C1EE01971F

[journal] RAJANGAMVINODH / 2015 / Synthesis and characterization of semiconducting porous carbon for energy applications and CO2 adsorption / Journal of Industrial and Engineering Chemistry / 한국공업화학회 32 : 273~281 / http://dx.doi.org/10.1016/j.jiec.2015.09.002

[journal] Dawson R / 2010 / High surface area conjugated microporous polymers : the importance of reaction solvent choice / Macromolecules 43 : 8524~ / https://doi.org/10.1021/ma101541h

[journal] Lindemann P / 2014 / Preparation of freestanding conjugated microporous polymer nanomembranes for gas separation / Chem Mater 26 : 7189~ / https://doi.org/10.1021/cm503924h

[journal] Zhu X / 2014 / Efficient CO2capture by a task-specific porous organic polymer bifunctionalized with carbazole and triazine groups / Chem Commun 50 : 7933~ / https://doi.org/10.1039/C4CC01588F

[journal] Saleh M / 2014 / Highly stable CO2/N2 and CO2/CH4 selectivity in hyper-cross-linked heterocyclic porous polymers / ACS Appl Mater Interfaces 6 : 7325~ / https://doi.org/10.1021/am500728q

[journal] Vinodh R / 2015 / A new strategy to synthesize hypercrosslinked conjugated polystyrene and its application towards CO2sorption / Fibers Polym 16 : 1458~ / https://doi.org/10.1007/s12221-015-5151-y

[journal] Vinodh R / 2015 / Microporous hypercross-linked conjugated quinonoid chromophores of anthracene : novel polymers for CO2adsorption / Chin J Polym Sci 33 : 224~ / https://doi.org/10.1007/s10118-015-1573-7

[journal] Song Q / 2014 / Controlled thermal oxidative crosslinking of polymers of intrinsic microporosity towards tunable molecular sieve membranes / Nat Commun 5 : 4813~ / https://doi.org/10.1038/ncomms5813

[journal] Patel HA / 2012 / Noninvasive functionalization of polymers of intrinsic microporosity for enhanced CO2capture / Chem Commun 48 : 9989~ / https://doi.org/10.1039/C2CC35392J

[journal] Patel HA / 2012 / High capacity carbon dioxide adsorption by inexpensive covalent organic polymers / J Mater Chem 22 : 8431~ / https://doi.org/10.1039/C2JM30761H

[journal] Furukawa H / 2009 / Storage of hydrogen, methane, and carbon dioxide in highly porous covalent organic frameworks for clean energy applications / J Am Chem Soc 131 : 8875~ / https://doi.org/10.1021/ja9015765

[journal] Hu L / 2016 / Hypercrosslinked polymers incorporated with imidazolium salts for enhancing CO2capture / Polym Eng Sci 56 : 573~ / https://doi.org/10.1002/pen.24282

[journal] Okay O / 2000 / Macroporous copolymer networks / Prog Polym Sci 25 : 711~ / https://doi.org/10.1016/S0079-6700(00)00015-0

[journal] Gokmen MT / 2012 / Porous polymer particles—a comprehensive guide to synthesis, characterization, functionalization and applications / Prog Polym Sci 37 : 365~ / https://doi.org/10.1016/j.progpolymsci.2011.07.006

[journal] Duranoglu D / 2012 / Synthesis and adsorption properties of polymeric and polymer-based hybrid adsorbent for hexavalent chromium removal / Chem Eng J 181–182 : 103~

[journal] Jianhan H / 2013 / Phenol adsorption on α, α′-dichloro-p-xylene(DCX)and 4, 4′-bis(chloromethyl)-1, 1′-biphenyl(BCMBP)modified XAD-4 resins from aqueous solutions / Chem Eng J 222 : 1~ / https://doi.org/10.1016/j.cej.2013.02.044

[journal] Xu S / 2013 / Recent development of hypercrosslinked microporous organic polymers / Macromol Rapid Commun 34 : 471~ / https://doi.org/10.1002/marc.201200788

[journal] Meng QB / 2014 / Lignin-based microporous materials as selective adsorbents for carbon dioxide separation / Chemsuschem 7 : 3312~ / https://doi.org/10.1002/cssc.201402879

[journal] Stankovich S / 2006 / Graphene-based composite materials / Nature 442 : 282~ / https://doi.org/10.1038/nature04969

[journal] Stankovich S / 2007 / Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide / Carbon 45 : 1558~ / https://doi.org/10.1016/j.carbon.2007.02.034

[journal] Brodie MBC / 1860 / Note sur un nouveau procede pour la purification et la desagragation du graphite / Ann Chim Phys 45 : 351~

[journal] Seredych M / 2009 / Role of graphite precursor in the performance of graphite oxides as ammonia adsorbents / Carbon 47 : 445~ / https://doi.org/10.1016/j.carbon.2008.10.020

[journal] Bissessur R / 2006 / Encapsulation of polyanilines into graphite oxide / Langmuir 22 : 1729~ / https://doi.org/10.1021/la0527339

[journal] Matsuo Y / 2005 / Preparation and characterization of silylated graphite oxide / Carbon 43 : 2875~ / https://doi.org/10.1016/j.carbon.2005.06.006

[journal] Morishige K / 2005 / Iron oxide pillared graphite / Langmuir 21 : 6277~ / https://doi.org/10.1021/la050544k

[journal] Petit C / 2009 / Graphite oxide/polyoxometalate nanocomposites as adsorbents of ammonia / J Phys Chem C 113 : 3800~ / https://doi.org/10.1021/jp8097044

[journal] Petit C / 2009 / MOF-graphite oxide composites : combining the uniqueness of graphene layers and metal-organic frameworks / Adv Mater 21 : 4753~ / https://doi.org/10.1002/adma.200901581

[journal] Hummers WS / 1958 / Preparation of graphite oxide / J Am Chem Soc 8 : 1339~ / https://doi.org/10.1021/ja01539a017

[journal] Chen Y / 2009 / Stable dispersions of graphene and highly conducting graphene films : a new approach to creating colloids of graphene monolayers / Chem Commun 30 : 4527~ / https://doi.org/10.1039/b907723e

[journal] Babu CM / 2017 / Organic functionalized Fe3O4/RGO nanocomposites for CO2adsorption / J Environ Chem Eng 5 : 2440~ / https://doi.org/10.1016/j.jece.2017.04.044

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