Effect of Oxyfluorination on Water Dispersion of Phthalocyanine Pigment

Lee-minkyu; Jin-Seok Bae; Taekyeong Kim; 안승현; 정민정; Lee， Young-Seak; Euigyung Jeong

Textile Coloration and Finishing

Abbr : Text. Color. and Finish.
2017, 29(4), pp.195-201
Publisher : The Korean Society Of Dyers And Finishers
Research Area : Dyeing Engineering

Lee-minkyu ¹, Jin-Seok Bae ², Taekyeong Kim ³, 안승현 ⁴, 정민정 ⁵, Lee， Young-Seak ⁶, Euigyung Jeong ⁷

¹경북대학교
²경북대학교
³경북대학교
⁴(주)잉크테크
⁵충남대학교
⁶충남대학교
⁷경북대학교

ABSTRACT

To study the effect of oxyfluorination on water dispersion of phthalocyanine blue(C.I. pigment blue 15:3), the pigment was oxyfluorinated using various oxygen to fluorine ratio of the reactant gas. After the oxyfluorination of the phthalocyanine blue pigment, no significant change in FT-IR spectra was observed, whereas XPS spectra showed the introduction of oxygen and fluorine containing functional groups. This suggests that the oxyfluorination of the pigment only occurred on the surface of the pigment particle and resulted in no significant change in UV-Vis spectra of the pigment. However, the oxyflurinated pigments showed improved water dispersion, compared to the non-treated pigment. Especially, when the oxygen to fluorine ratio was 47:3, the water dispersion of the oxyfluorinated pigments sinificantly increased, compared to the non-treated pigments. This suggests that the oxyfluorination of the phthalocyanine blue pigment has a potential to be used as a water dispersion improving method.
KEYWORDS

digital textile printing, pigment ink, phthalocyanine blue, oxyfluorination, water dispersion
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