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Synthesis and Dyeing Properties of Red Disperse Dyes Derived from Diaminopyridines

  • Textile Coloration and Finishing
  • Abbr : Text. Color. and Finish.
  • 2005, 17(6), pp.1-10
  • Publisher : The Korean Society Of Dyers And Finishers
  • Research Area : Engineering > Fiber Engineering > Dyeing Engineering

박종호 1 Joonseok Koh ORD ID 1 배진석 2 Sung-Dong Kim 1

1건국대학교
2한국염색기술연구소

Accredited

ABSTRACT

dyes derived from heterocyclic compounds such as phenylindole, pyridone, diaminopyridine, and carbazole have been known to exhibit high light fastness and bathochromic shift compared to the corresponding aminoazobenzene. The synthetic method to obtain diaminopyridine derivatives, which can be used as coupling components, was chlorination of pyridone with phosphorous oxychloride, followed by substitution with various primary amines. Four azo disperse dyes were synthesized by coupling four diaminopyridines with 2-cyano-4-nitroaniline as a diazo component. Structures of these dyes were confirmed by 1H NMR spectroscopy. The wavelengths of maximum absorption of the synthesized disperse dyes were in the range of 517∼528nm, and molar extinction coefficients were 45,700∼50,100. The dyeability of four disperse dyes toward PET fiber was generally good. Wash and rubbing fastnesses were excellent, while light and dry heat fastness were good.

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