@article{ART001083921},
author={박건용 and 김재현},
title={Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9)},
journal={Textile Coloration and Finishing },
issn={1229-0033},
year={2007},
volume={19},
number={4},
pages={18-25}
TY - JOUR
AU - 박건용
AU - 김재현
TI - Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9)
JO - Textile Coloration and Finishing
PY - 2007
VL - 19
IS - 4
PB - The Korean Society Of Dyers And Finishers
SP - 18
EP - 25
SN - 1229-0033
AB - Kinetics and mechanism for alkaline hydrolysis of C. I. Disperse Green 9(G-9) of dinitrothiophene disperse dye were investigated. As soon as G-9 contacted with alkali, instant and continuous decreases of color strength of G-9 followed with increasing time. The hydrolysis rate of G-9 increased with increasing alkali, and it was found that alkali appeared first order dependence. The observed rate constants obtained from hydrolysis of various amount of dye were similar values, and calculation of initial rates showed that G-9 hydrolyzed by first order reaction for dye. Therefore it was confirmed that the overall reaction was second order, SN2 of nucleophilic substitution reaction. Increasing temperature enhanced the hydrolysis of G-9. From the results of hydrolysis performed at various temperatures, it was obtained that activation energy(Ea) was 12.6 kcal/mole, enthalpy of reaction(ΔH) was 12.0 kcal/mole, and entropy of reaction(ΔS) was 29.8 J/molK.
KW - Dinitrothiophene disperse dyes;Kinetics and mechanism for alkaline hydrolysis;SN2 of nucleophilic substitution reaction;Activation energy(Ea)
DO -
UR -
ER -
박건용 and 김재현. (2007). Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9). Textile Coloration and Finishing , 19(4), 18-25.
박건용 and 김재현. 2007, "Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9)", Textile Coloration and Finishing , vol.19, no.4 pp.18-25.
박건용, 김재현 "Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9)" Textile Coloration and Finishing 19.4 pp.18-25 (2007) : 18.
박건용, 김재현. Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9). 2007; 19(4), 18-25.
박건용 and 김재현. "Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9)" Textile Coloration and Finishing 19, no.4 (2007) : 18-25.
박건용; 김재현. Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9). Textile Coloration and Finishing , 19(4), 18-25.
박건용; 김재현. Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9). Textile Coloration and Finishing . 2007; 19(4) 18-25.
박건용, 김재현. Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9). 2007; 19(4), 18-25.
박건용 and 김재현. "Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9)" Textile Coloration and Finishing 19, no.4 (2007) : 18-25.
