Flame Retardancy of Cellulose Fabrics Treated with 3-(Hydroxyphenyl Phosphinyl) Propanoic Acid

Lianping Zhang; Sam-Soo Kim (김삼수); Jaewoong Lee (이재웅)

Flame Retardancy of Cellulose Fabrics Treated with 3-(Hydroxyphenyl Phosphinyl) Propanoic Acid

Textile Coloration and Finishing
Abbr : Text. Color. and Finish.
2008, 20(5), pp.1~6
Publisher : The Korean Society Of Dyers And Finishers
Research Area : Engineering > Fiber Engineering > Dyeing Engineering

Lianping Zhang ¹, Sam-Soo Kim ¹, Jaewoong Lee ¹

¹영남대학교

Accredited

ABSTRACT

3-(Hydroxyphenyl phosphinyl) propanoic acid (HPPA) has been one of the most commonly used durable flame retardant agents for polyethylene terephthalate (PET) for many years. We intended to explore the application of HPPA to cellulose fabrics as formaldehyde-free phosphorus based flame retardants (FRs) through green chemistry process. The flame retardancy of the flame-retardant treated cellulose fabrics were characterized by using inductively coupled plasma spectroscopy (ICP) and limiting oxygen index (LOI). Structural changes of the treated cellulose fabrics were carried out by thermogravimetric analysis (TGA) and Fourier transform infrared (FT-IR) spectroscopy. To enhance the flame retardancy of HPPA treated cellulose fibers, glycerol polyglycidyl ether (GPE), a crosslinking agent was employed. Both HPPA and GPE treated cotton fabric imparted an LOI value over 26.

KEYWORDS

flame retardant, cellulose, crosslinking agent, cotton, coupling agent, limiting oxygen index

Journal Copyright Policy

No CCL information provided

Citation status

* References for papers published after 2025 are currently being built.

[journal] S. V. Levchik / 2006 / A Review of Recent Progress in Phosphorus-based Flame Retardants / J. Fire Sci : 345~364

[journal] C. Q. Yang / 1997 / Ester Crosslinking of Cotton Fabric by Polymeric Carboxylic Acids and Citric Acid / Textile Research Journal 67(5) : 334~342

[journal] C. Q. Yang / 2003 / Crossliking Cotton with Poly(itaconic acid) and In Situ Polymerization of Itaconic Acid: Fabric Mechanical Strength Retention / J. Appl. Polym. Sci : 2023~2030

[journal] C. Q. Yang / 1996 / Infrared Spectroscopy Studies of the Cyclic Anhydride as the Intermediate for the Ester Crosslinking of Cotton Cellulose by Polycarboxylic Acids. II. Comparison of Different Polycarboxylic Acids / J. Polym. Sci : 1573~1580

[journal] C. Q. Yang / 1996 / Formation of Cyclic Anhydride Intermediates and Esterification of Cotton Cellulose by Multifunctional Carboxylic Acids: An Infrared Spectroscopy Study / Textile Research Journal 66(9) : 595~603

[journal] J. Lee / 2007 / Antimicrobial Fibers Created via Polycarboxylic Acid Durable Press Finishing / Textile Research Journal 77(8) : 604~611

[journal] S. Yang / 2007 / Flame Retardant Polyesters. I. Phosphorous Flame Retardants / J. Appl. Polym. Sci : 2870~2874

[journal] S. Yang / 2007 / Flame Retardant Polyesters. II. Polyester Polymers / J. Appl. Polym. Sci : 1274~1280

[journal] S. Yang / 2007 / Flame Retardant Polyesters. III. Fibers / J. Appl. Polym. Sci : 2297~2300

[book] G.Joseph / 2000 / Fire Retardancy of Polymeric Materials / Marcel Dekker,Inc.,New York : 148~206

[journal] S. Gaan / 2007 / Effect of Phosphorus Flame Retardants on Thermo-oxidative Decomposition of Cotton / Polym. Degrad. Stab : 968~974

[journal] S. Gaan / 2007 / Effect of Phosphorus and Nitrogen on Flame Retardant Cellulose: A Study of Phosphorus Compounds / J. Anal. Appl. Pyrolysis : 371~377

KJCKorea
Journal Central

Textile Coloration and Finishing KCI Impact Factor : 0.0