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@article{ART001645803},
author={Minkwan Kim and Han Do Ghim},
title={Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -},
journal={Textile Coloration and Finishing },
issn={1229-0033},
year={2012},
volume={24},
number={1},
pages={33-38}

TY - JOUR
AU - Minkwan Kim
AU - Han Do Ghim
TI - Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -
JO - Textile Coloration and Finishing
PY - 2012
VL - 24
IS - 1
PB - The Korean Society Of Dyers And Finishers
SP - 33
EP - 38
SN - 1229-0033
AB - In this study, to increase flame retardation of poly(ethylene terephthalate) (PET) in burning, bisphenol A bis(diphenyl phosphate) (BDP), a well known flame retardant containing phosphorous, was reacted on end groups of PET by radical pathway. End-capping mechanism of PET with BDP was suggested and confirmed by spectroscopic and thermal analysis. From 400 MHz 31P solid state FT-NMR spectrum of end-capped PET (PET-BDP), phosphorus spectra peak in BDP was found at ca. -20 ppm. Furthermore, P-C bond stretching vibration peaks were found ca. 600 cm-1 in FT-IR spectrums of PET-BDP. These results showed that BDP can be chemically added on end groups of PET by our method. Thermal characteristics of pure PET (pPET) and PET-BDP were measured and evaluated by TGA analysis. There was not significant changes in thermal characteristics of PET-BDP compared to that of pPET.
KW - poly(ethylene terephthalate);bisphenol A bis(diphenyl phosphate);radical graft reaction;flame retardant;31P solid state FT-NMR;TGA analysis
DO -
UR -
ER -

Minkwan Kim and Han Do Ghim. (2012). Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -. Textile Coloration and Finishing , 24(1), 33-38.

Minkwan Kim and Han Do Ghim. 2012, "Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -", Textile Coloration and Finishing , vol.24, no.1 pp.33-38.

Minkwan Kim, Han Do Ghim "Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -" Textile Coloration and Finishing 24.1 pp.33-38 (2012) : 33.

Minkwan Kim, Han Do Ghim. Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -. 2012; 24(1), 33-38.

Minkwan Kim and Han Do Ghim. "Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -" Textile Coloration and Finishing 24, no.1 (2012) : 33-38.

Minkwan Kim; Han Do Ghim. Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -. Textile Coloration and Finishing , 24(1), 33-38.

Minkwan Kim; Han Do Ghim. Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -. Textile Coloration and Finishing . 2012; 24(1) 33-38.

Minkwan Kim, Han Do Ghim. Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -. 2012; 24(1), 33-38.

Minkwan Kim and Han Do Ghim. "Radical Addition Reaction of Phosphorous based Flame Retardant with End Groups of PET (1) - Reaction of Bisphenol A bis(diphenyl phosphate) -" Textile Coloration and Finishing 24, no.1 (2012) : 33-38.