@article{ART002063836},
author={JUN， KUN and Gwon Seon-yeong and KIM SUNG HOON},
title={Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye},
journal={Textile Coloration and Finishing },
issn={1229-0033},
year={2015},
volume={27},
number={4},
pages={270-274}
TY - JOUR
AU - JUN， KUN
AU - Gwon Seon-yeong
AU - KIM SUNG HOON
TI - Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye
JO - Textile Coloration and Finishing
PY - 2015
VL - 27
IS - 4
PB - The Korean Society Of Dyers And Finishers
SP - 270
EP - 274
SN - 1229-0033
AB - Molecules always show broad absorption band envelopes, and this results from the vibrational properties of bonds. The width of an absorption band can have an important influence on the color of a dye. A narrow band imparts a bright, spectrally pure color to the dye, whereas a broad band can give the same hue, but with a much duller appearance. Typically, half-band widths of cyanine dyes are about 25nm compared to value of over 50nm for typical merocyanine dyes. Thus, cyanine dyes are exceptionally bright. The factors influencing the width of an absorption band can be understood with reference to the Morse curves. The width of the absorption band depends on how closely the bond order of the molecules in the first excited state resembles that in the ground state. We have quantitatively evaluated the "molecular structure-absorption band shape" relationship of dye molecules by means of Pariser-Parr-Pople Molecular Orbital Method(PPP-MO).
KW - absorption band shape;bond order;Pariser-Parr-Pople molecular orbital method(PPP-MO);merocyanine dye;cyanine dye
DO -
UR -
ER -
JUN， KUN, Gwon Seon-yeong and KIM SUNG HOON. (2015). Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye. Textile Coloration and Finishing , 27(4), 270-274.
JUN， KUN, Gwon Seon-yeong and KIM SUNG HOON. 2015, "Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye", Textile Coloration and Finishing , vol.27, no.4 pp.270-274.
JUN， KUN, Gwon Seon-yeong, KIM SUNG HOON "Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye" Textile Coloration and Finishing 27.4 pp.270-274 (2015) : 270.
JUN， KUN, Gwon Seon-yeong, KIM SUNG HOON. Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye. 2015; 27(4), 270-274.
JUN， KUN, Gwon Seon-yeong and KIM SUNG HOON. "Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye" Textile Coloration and Finishing 27, no.4 (2015) : 270-274.
JUN， KUN; Gwon Seon-yeong; KIM SUNG HOON. Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye. Textile Coloration and Finishing , 27(4), 270-274.
JUN， KUN; Gwon Seon-yeong; KIM SUNG HOON. Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye. Textile Coloration and Finishing . 2015; 27(4) 270-274.
JUN， KUN, Gwon Seon-yeong, KIM SUNG HOON. Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye. 2015; 27(4), 270-274.
JUN， KUN, Gwon Seon-yeong and KIM SUNG HOON. "Relationship between the Molecular Structure and the Absorption Band Shape of Organic Dye" Textile Coloration and Finishing 27, no.4 (2015) : 270-274.
