Synthesis of Novel Morpholine Appended Crystal violet lactone Derivatives and an Investigation of their Thermochromic Behavior

Myeong Jin Kim (김명진); Palanisamy Muthukumar; Satheshkumar Angupillai; Young-A Son (손영아)

doi:10.5764/TCF.2018.30.1.1

Synthesis of Novel Morpholine Appended Crystal violet lactone Derivatives and an Investigation of their Thermochromic Behavior

Textile Coloration and Finishing
Abbr : Text. Color. and Finish.
2018, 30(1), pp.1-8
DOI : 10.5764/TCF.2018.30.1.1
Publisher : The Korean Society Of Dyers And Finishers
Research Area : Engineering > Fiber Engineering > Dyeing Engineering
Received : October 23, 2017
Accepted : December 22, 2017
Published : March 27, 2018

Myeong Jin Kim ¹, Palanisamy Muthukumar ², Satheshkumar Angupillai ¹, Young-A Son ¹

¹Chungnam National University
²Bannari Amman Institute of Technology

Accredited

ABSTRACT

In the present study, three morpholine substituted crystal violet lactone (CVL) have been synthesized to monitor the thermochromic property. This work is explaining the role of substituent on the lactone ring. The methyl substituents induced greater chromic effects than the chloro substituents. Furthermore, the three-component mixtures that contained CVL, bisphenol-A, and methyl stearate were used to analyse the thermochromic effect of the CVLs as bulk samples with various temperature. The thermochromic properties of the CVLs were evaluated using solid-state UV-Vis and FT-IR spectroscopic techniques. Finally, one of the synthesized CVL has been successfully converted into the form of a test paper similar to pH paper for use as thermal indicators.

KEYWORDS

CVL, leuco dyes, morpholine, substituent effect, thermal indicator

Citation status

* References for papers published after 2023 are currently being built.

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Synthesis of Novel Morpholine Appended Crystal violet lactone Derivatives and an Investigation of their Thermochromic Behavior

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Synthesis of Novel Morpholine Appended Crystal violet lactone Derivatives and an Investigation of their Thermochromic Behavior

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