본문 바로가기
  • Home

Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide

  • Textile Coloration and Finishing
  • Abbr : Text. Color. and Finish.
  • 2019, 31(3), pp.165-176
  • DOI : 10.5764/TCF.2019.31.3.165
  • Publisher : The Korean Society Of Dyers And Finishers
  • Research Area : Engineering > Fiber Engineering > Dyeing Engineering
  • Received : August 22, 2019
  • Accepted : September 18, 2019
  • Published : September 27, 2019

Ji-Hyeon Park 1 Jong Seung Park 1 Pil-Jun Choi 2 Jae-Wang Ko 2 Jae-Yeon Lee 2 Suk-Hun Sur 2

1부산대학교 유기소재시스템공학과
2한국신발피혁연구원

Accredited

ABSTRACT

Polyurethane-ureas(PUUs) were prepared from 4,4'-Methylenebis(cyclohexyl isocyanate) and various diols including isosorbide. Isosorbide is starch-derived monomer that exhibit a wide range of glass transition temperature and are therefore able to be used in many applications. PUU was synthesized by a pre-polymer polymerization using a catalyst. Successful synthesis of the PUU was characterized by fourier transform-infrared spectroscopy. Thermal properties were determined by differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical analysis. It was found that by tuning isosorbide content in the resin, their glass transition temperature(Tg) slightly decreased. Physical properties were also determined by tensile strength and X-ray diffraction. There is no significant differences between petroleum-derived diol and isosorbide in XRD analysis. Moreover, their physical and optical properties were determined. The result showed that the poly(tetramethylene ether glycol)/isosorbide-based PUU exhibited enhanced tensile strength, transmittance, transparency and biodegradability compared to the existing diols. After 11 weeks composting, the biodegradability of blends increased in ISB-PUU. The morphology of the fractured surface of blend films were investigated by scanning electron microscopy.

Citation status

* References for papers published after 2022 are currently being built.