@article{ART002506169},
author={Ji-Hyeon Park and Jong Seung Park and Pil-Jun Choi and Jae-Wang Ko and Jae-Yeon Lee and Suk-Hun Sur},
title={Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide},
journal={Textile Coloration and Finishing },
issn={1229-0033},
year={2019},
volume={31},
number={3},
pages={165-176},
doi={10.5764/TCF.2019.31.3.165}
TY - JOUR
AU - Ji-Hyeon Park
AU - Jong Seung Park
AU - Pil-Jun Choi
AU - Jae-Wang Ko
AU - Jae-Yeon Lee
AU - Suk-Hun Sur
TI - Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide
JO - Textile Coloration and Finishing
PY - 2019
VL - 31
IS - 3
PB - The Korean Society Of Dyers And Finishers
SP - 165
EP - 176
SN - 1229-0033
AB - Polyurethane-ureas(PUUs) were prepared from 4,4'-Methylenebis(cyclohexyl isocyanate) and various diols including isosorbide. Isosorbide is starch-derived monomer that exhibit a wide range of glass transition temperature and are therefore able to be used in many applications. PUU was synthesized by a pre-polymer polymerization using a catalyst. Successful synthesis of the PUU was characterized by fourier transform-infrared spectroscopy. Thermal properties were determined by differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical analysis. It was found that by tuning isosorbide content in the resin, their glass transition temperature(Tg) slightly decreased. Physical properties were also determined by tensile strength and X-ray diffraction. There is no significant differences between petroleum-derived diol and isosorbide in XRD analysis. Moreover, their physical and optical properties were determined. The result showed that the poly(tetramethylene ether glycol)/isosorbide-based PUU exhibited enhanced tensile strength, transmittance, transparency and biodegradability compared to the existing diols. After 11 weeks composting, the biodegradability of blends increased in ISB-PUU. The morphology of the fractured surface of blend films were investigated by scanning electron microscopy.
KW - isosorbide;polyurethane;biopolymer;biodegradability;coating
DO - 10.5764/TCF.2019.31.3.165
ER -
Ji-Hyeon Park, Jong Seung Park, Pil-Jun Choi, Jae-Wang Ko, Jae-Yeon Lee and Suk-Hun Sur. (2019). Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide. Textile Coloration and Finishing , 31(3), 165-176.
Ji-Hyeon Park, Jong Seung Park, Pil-Jun Choi, Jae-Wang Ko, Jae-Yeon Lee and Suk-Hun Sur. 2019, "Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide", Textile Coloration and Finishing , vol.31, no.3 pp.165-176. Available from: doi:10.5764/TCF.2019.31.3.165
Ji-Hyeon Park, Jong Seung Park, Pil-Jun Choi, Jae-Wang Ko, Jae-Yeon Lee, Suk-Hun Sur "Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide" Textile Coloration and Finishing 31.3 pp.165-176 (2019) : 165.
Ji-Hyeon Park, Jong Seung Park, Pil-Jun Choi, Jae-Wang Ko, Jae-Yeon Lee, Suk-Hun Sur. Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide. 2019; 31(3), 165-176. Available from: doi:10.5764/TCF.2019.31.3.165
Ji-Hyeon Park, Jong Seung Park, Pil-Jun Choi, Jae-Wang Ko, Jae-Yeon Lee and Suk-Hun Sur. "Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide" Textile Coloration and Finishing 31, no.3 (2019) : 165-176.doi: 10.5764/TCF.2019.31.3.165
Ji-Hyeon Park; Jong Seung Park; Pil-Jun Choi; Jae-Wang Ko; Jae-Yeon Lee; Suk-Hun Sur. Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide. Textile Coloration and Finishing , 31(3), 165-176. doi: 10.5764/TCF.2019.31.3.165
Ji-Hyeon Park; Jong Seung Park; Pil-Jun Choi; Jae-Wang Ko; Jae-Yeon Lee; Suk-Hun Sur. Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide. Textile Coloration and Finishing . 2019; 31(3) 165-176. doi: 10.5764/TCF.2019.31.3.165
Ji-Hyeon Park, Jong Seung Park, Pil-Jun Choi, Jae-Wang Ko, Jae-Yeon Lee, Suk-Hun Sur. Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide. 2019; 31(3), 165-176. Available from: doi:10.5764/TCF.2019.31.3.165
Ji-Hyeon Park, Jong Seung Park, Pil-Jun Choi, Jae-Wang Ko, Jae-Yeon Lee and Suk-Hun Sur. "Preparation and Comparison the Physical Properties of Polyurethane-Urea Using Biomass Derived Isosorbide" Textile Coloration and Finishing 31, no.3 (2019) : 165-176.doi: 10.5764/TCF.2019.31.3.165