@article{ART002629117},
author={Jeong-Hwan Kim and Jang, Jin-Ho},
title={Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine},
journal={Textile Coloration and Finishing },
issn={1229-0033},
year={2020},
volume={32},
number={3},
pages={150-157},
doi={10.5764/TCF.2020.32.3.150}
TY - JOUR
AU - Jeong-Hwan Kim
AU - Jang, Jin-Ho
TI - Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine
JO - Textile Coloration and Finishing
PY - 2020
VL - 32
IS - 3
PB - The Korean Society Of Dyers And Finishers
SP - 150
EP - 157
SN - 1229-0033
AB - Hexachloro-cyclophosphazene(HCCP), a formaldehyde-free flame retardant (FR), was steam-cured with triethanol amine(TEA) to impart durable flame-retardancy to cotton fabrics. While the HCCP treatment alone showed very limited resistance to repeated laundering cycles, the addition of TEA substantially improved the laundering durability of the FR cotton up to twenty laundering cycles. The extended washing resistance was accomplished by the increased nucleophilic substitution of unreacted P-Cl groups in HCCP by the TEA resulting in the more densely crosslinked FR networks. With increasing molar ratio of TEA to the HCCP up to 2, the flame retarding effectivity and the synergistic effectiveness improved to 2.8 and 1.8 respectively. TGA and microscale combustion calorimetry verified the pyrolysis and combustion behaviors of the FR-cotton, which showed lower maximum pyrolysis and combustion temperatures together with substantially decreased peak pyrolysis and heat release rate, synergistically yielding larger amounts of carbonaceous chars. The formaldehyde-free HCCP and TEA can be a durable FR finishing agents for cotton fabrics acting through a solid-phase flame-retarding mechanism.
KW - formaldehyde-free;durable;flame retardant;cotton;crosslink
DO - 10.5764/TCF.2020.32.3.150
ER -
Jeong-Hwan Kim and Jang, Jin-Ho. (2020). Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine. Textile Coloration and Finishing , 32(3), 150-157.
Jeong-Hwan Kim and Jang, Jin-Ho. 2020, "Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine", Textile Coloration and Finishing , vol.32, no.3 pp.150-157. Available from: doi:10.5764/TCF.2020.32.3.150
Jeong-Hwan Kim, Jang, Jin-Ho "Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine" Textile Coloration and Finishing 32.3 pp.150-157 (2020) : 150.
Jeong-Hwan Kim, Jang, Jin-Ho. Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine. 2020; 32(3), 150-157. Available from: doi:10.5764/TCF.2020.32.3.150
Jeong-Hwan Kim and Jang, Jin-Ho. "Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine" Textile Coloration and Finishing 32, no.3 (2020) : 150-157.doi: 10.5764/TCF.2020.32.3.150
Jeong-Hwan Kim; Jang, Jin-Ho. Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine. Textile Coloration and Finishing , 32(3), 150-157. doi: 10.5764/TCF.2020.32.3.150
Jeong-Hwan Kim; Jang, Jin-Ho. Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine. Textile Coloration and Finishing . 2020; 32(3) 150-157. doi: 10.5764/TCF.2020.32.3.150
Jeong-Hwan Kim, Jang, Jin-Ho. Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine. 2020; 32(3), 150-157. Available from: doi:10.5764/TCF.2020.32.3.150
Jeong-Hwan Kim and Jang, Jin-Ho. "Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine" Textile Coloration and Finishing 32, no.3 (2020) : 150-157.doi: 10.5764/TCF.2020.32.3.150
