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Amino Silane, Vinyl Silane, TESPD, ZS(TESPD/Zinc Complex) Effects on Carbon Black/Clay Filled Chlorobutyl Rubber(CIIR) Compounds Part I: Effects on Hard Clay/Carbon Black Filled Compounds

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2009, 10(2), pp.101-108
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General

김광제 1

1동아타이어공업(주)

Candidate

ABSTRACT

Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/hard clay/carbon black (CB) compound and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. In hard clay/CB filled system, only ZS silane added compound shows both lower Mooney viscosity and extrusion torque while vinyl silane added compound showed only a lower extrusion torque. All the ZS added compounds showed the lowest viscosity among them. The silane added compounds showed an increased modulus. In ‘fatigue to failure’ count test, the ZS added compound showed superior counts compared to other silane (amino, vinyl, TESPD) added compounds. The mechanical properties were significantly increased when the S2 and ZS were added into CIIR/hard clay/CB compound. The ZS added compounds showed a significant improvement on elongation modulus.

Citation status

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