Effect of graphite oxide on photodegradation behavior of poly(vinyl alcohol)/graphite oxide composite hydrogels

문영이; 윤주미; Kim， Hyung-il (김형일); Lee, Young-Seak (이영석)

Effect of graphite oxide on photodegradation behavior of poly(vinyl alcohol)/graphite oxide composite hydrogels

Carbon Letters
Abbr : Carbon Lett.
2011, 12(3), pp.138-142
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General

문영이 ¹, 윤주미 ¹, Kim， Hyung-il ¹, Lee, Young-Seak ¹

¹충남대학교

Candidate

ABSTRACT

Poly(vinyl alcohol) (PVA) composites with various graphite oxide (GO) contents (0 to 10 wt%) were prepared by sonicating the mixture of PVA and GO, followed by crosslinking with glutaraldehyde. GO was pre-treated with oxyfluorination (O2:F2 = 8:2) in order to modify the surface of GO to allow it to carry hydrophilic functional groups. PVA/GO composite hydrogels were characterized by scanning electron microscopy and Fourier-transform infrared spectrometer (FT-IR). The morphology of the PVA/GO composite hydrogels and the variations in soluble gel portion were investigated under various GO contents and UV irradiation doses. The variation in the chemical structure of photo degraded PVA/GO composite hydrogels was studied by FT-IR. The photochemical stability of PVA/GO composite hydrogels under UV irradiation was found to improve noticeably with increasing content of uniformly dispersed GO.

KEYWORDS

photochemical stability, graphite oxide, poly(vinyl alcohol)

Citation status

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