Parametric Study of Methanol Chemical Vapor Deposition Growth for Graphene

조현진; Changhyup Lee; In Seoup Oh; Sungchan Park; Hwan Chul Kim (김환철); 김명종

doi:10.5714/CL.2012.13.4.205

Parametric Study of Methanol Chemical Vapor Deposition Growth for Graphene

Carbon Letters
Abbr : Carbon Lett.
2012, 13(4), pp.205-211
DOI : 10.5714/CL.2012.13.4.205
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General

조현진 ¹, Changhyup Lee ², In Seoup Oh ², Sungchan Park ³, Hwan Chul Kim ¹, 김명종 ⁴

¹전북대학교
²Korea Institute of Science and Technology
³Chonbuk National University
⁴한국과학기술연구원

Accredited

ABSTRACT

Methanol as a carbon source in chemical vapor deposition (CVD) graphene has an advantage over methane and hydrogen in that we can avoid optimizing an etching reagent condition. Since methanol itself can easily decompose into hydrocarbon and water (an etching reagent) at high temperatures [1], the pressure and the temperature of methanol are the only parameters we have to handle. In this study, synthetic conditions for highly crystalline and large area graphene have been optimized by adjusting pressure and temperature; the effect of each parameter was analyzed systematically by Raman, scanning electron microscope,transmission electron microscope, atomic force microscope, four-point-probe measurement,and UV-Vis. Defect density of graphene, represented by D/G ratio in Raman, decreased with increasing temperature and decreasing pressure; it negatively affected electrical conductivity. From our process and various analyses, methanol CVD growth for graphene has been found to be a safe, cheap, easy, and simple method to produce high quality, large area, and continuous graphene films.

KEYWORDS

graphene, synthesis, methanol, low pressure chemical vapor deposition, large area

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[journal] Oshima H / 2008 / Novel and simple synthesis method for submillimeter long vertically aligned singlewalled carbon nanotubes by no-flow alcohol catalytic chemical vapor deposition / Jpn J Appl Phys 47 : 1982~

[journal] Novoselov KS / 2004 / Electric field effect in atomically thin carbon films / Science 306 : 666~

[journal] Gaim AK / 2007 / The rise of graphene / Nat Mater 6 : 183~

[book] Rocha CG / 2012 / Tailoring the physical properties of graphene, In Graphene: synthesis and applications. Nanomaterials and their applications / CRC Press : 1~

[journal] Hernandez Y / 2008 / High-yield production of graphene by liquid-phase exfoliation of graphite / Nat Nanotechnol 3 : 563~

[journal] Kim KS / 200902 / Large-scale pattern growth of graphene films for stretchable transparent electrodes / NATURE / NATURE PUBLISHING GROUP 457(7230) : 706~710

[journal] Li X / 2009 / Large-area synthesis of high quality and uniform graphene films on copper foils / Science 324 : 1312~

[journal] Lu X / 1999 / Tailoring graphite with the goal of achieving single sheets / Nanotechnology 10 : 269~

[journal] Berger C / 2004 / Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene based nanoelectronics / J Phys Chem B 108 : 19912~

[journal] Bae S / 2010 / Roll-to-roll production of 30-inch graphene films for transparent electrodes / Nat Nanotechnol 5 : 574~

[journal] 안종현 / 201111 / Stretchable Graphene Transistors with Printed Dielectrics and Gate Electrodes / NANO LETTERS / AMER CHEMICAL SOC 11(11) : 4642~4646

[journal] 김봉훈 / 201109 / Stretchable, Transparent Graphene Interconnects for Arrays of Microscale Inorganic Light Emitting Diodes on Rubber Substrates / NANO LETTERS / AMER CHEMICAL SOC 11(9) : 3881~3886

[journal] 안종현 / 201112 / High-performance graphene-based transparent flexible heaters / NANO LETTERS / AMER CHEMICAL SOC 11(12) : 5154~5158

[journal] 유진 / 201104 / Ultrathin Planar Graphene Supercapacitors / NANO LETTERS / AMER CHEMICAL SOC 11(4) : 1423~1427

[journal] Wang Y / 2011 / Superelastic graphene ripples for flexible strain sensors / ACS Nano 5 : 3645~

[journal] Bunch JS / 2008 / Impermeable atomic membranes from graphene sheets / Nano Lett 8 : 2458~

[journal] Wang Z / 2010 / A high performance top-gate graphene field-effect transistor based frequency doubler / Appl Phys Lett 96 : 173104~

[journal] Jang BZ / 2008 / Processing of nanographene platelets (NGPs) and NGP nanocomposites: a review / J Mater Sci 43 : 5092~

[journal] Miyata Y / 2010 / A simple alcohol-chemical vapor deposition synthesis of single-layer graphenes using flash cooling / Appl Phys Lett 96 : 263105~

[journal] Srivastava A / 2010 / Novel liquid precursor-based facile synthesis of large-area continuous, single and few-layer graphene films / Chem Mater 22 : 3457~

[journal] Dong X / 2011 / Growth of large-sized graphene thin-films by liquid precursor- based chemical vapor deposition under atmospheric pressure / Carbon 49 : 3672~

[journal] Guermoune A / 2011 / Chemical vapor deposition synthesis of graphene on copper with methanol, ethanol, and propanol precursors / Carbon 49 : 4204~

[journal] Nair RR / 2008 / Fine structure constant defines visual transparency of graphene / Science 320 : 1308~

[journal] Li X / 2009 / Evolution of graphene growth on Ni and Cu by carbon isotope labeling / Nano Lett 9 : 4268~

[journal] Li X / 2009 / Transfer of large-area graphene films for highperformance transparent conductive electrodes / Nano Lett 9 : 4359~

[journal] Zhang Y / 2011 / Defectlike structures of graphene on copper foils for strain relief investigated by high-resolution scanning tunneling microscopy / ACS Nano 5 : 4014~

[journal] Tuinstra F / 1970 / Raman spectrum of graphite / J Chem Phys 53 : 1126~

[journal] Nemanich RJ / 1979 / First- and second-order Raman scatter ing from finite-size crystals of graphite / Phys Rev B 20 : 2~

[journal] Ferrari AC / 2006 / Raman spectrum of graphene and graphene layers / Phys Rev Lett 97 : 187401~

[journal] Li X / 2011 / Large-area graphene single crystals grown by low-pressure chemical vapor deposition of methane on copper / J Am Chem Soc 133 : 2816~

[journal] Dai H. / 2001 / Nanotube growth and characterization, Carbon nanotubes: synthesis, structure, properties, and applications / Topics in Applied Physics / Springer 80

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 4.82

Parametric Study of Methanol Chemical Vapor Deposition Growth for Graphene

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Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2023-01-02)

Total Citation Counts(KCI+WOS) (12) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 4.82

Parametric Study of Methanol Chemical Vapor Deposition Growth for Graphene

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WoS Citation Counts (12) This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2023-01-02)

Total Citation Counts(KCI+WOS) (12) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

REFERENCES (31) * References for papers published after 2023 are currently being built.

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This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2023-01-02)

* References for papers published after 2023 are currently being built.