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Comparative studies of porous carbon nanofibers by various activation methods

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2013, 14(3), pp.180-185
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General

이혜민 1 Kim Hong-Gun 2 강효랑 3 An Kay-Hyeok 1 KIM Byung-Joo 1

1(재) 한국탄소융합기술원
2전주대학교
3삼성종합기술원

Accredited

ABSTRACT

In this study, activated carbons nanofibers (ACNFs) were prepared from polyacrylonitrile-based nanofibers by physical (H2O and CO2) and chemical (KOH) activation. The surface and structural characteristics of the porous carbon were observed by scanning electron microscopy and X-ray diffraction, respectively. Pore characteristics were investigated by N2/77K adsorption isotherms. The specific surface area of the physically ACNFs was increased up to 2400 m2/g and the ACNFs were found to be mainly composed of micropore structures. Chemical activation using KOH produced ACNFs with high specific surface area (up to 2500 m2/g), and the micropores were mainly found in the ACNFs. The physically and chemically ACNFs showed both mainly type I from the International Union of Pure and Applied Chemistry classification.

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