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Cu2+ ion reduction in wastewater over RDF-derived char

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2016, 18(), pp.49-55
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General

Hyung Won Lee 1 Rae-su Park 2 Sung Hoon Park 3 Jung, Sangchul 3 Jeon Jong Ki 4 Kim Sang Chai 5 Jin Do Jung 6 Won-Geun Choi 7 Park Young Kwon 8

1서울시립대학교 환경공학과
2조선이공대학교
3순천대학교
4공주대학교
5목포대학교
6호서대학교
7호서대학교 기후변화융합기술학과
8서울시립대학교

Accredited

ABSTRACT

Refuse-derived fuel (RDF) produced using municipal solid waste was pyrolyzed to produce RDF char. For the first time, the RDF char was used to remove aqueous copper, a representative heavy metal water pollutant. Activation of the RDF char using steam and KOH treatments was performed to change the specific surface area, pore volume, and the metal cation quantity of the char. N2 sorption, Inductively Coupled Plasma-Atomic Emission Spectrometer (ICP-AES), and Fourier transform infrared spectroscopy were used to characterize the char. The optimum pH for copper removal was shown to be 5.5, and the steam-treated char displayed the best copper removal capability. Ion exchange between copper ions and alkali/alkaline metal cations was the most important mechanism of copper removal by RDF char, followed by adsorption on functional groups existing on the char surface. The copper adsorption behavior was represented well by a pseudo-second-order kinetics model and the Langmuir isotherm. The maximum copper removal capacity was determined to be 38.17 mg/g, which is larger than those of other low-cost char adsorbents reported previously.

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Total Citation Counts(KCI+WOS) (9) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (10) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

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