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Physicochemical properties and methane adsorption performance of activated carbon nanofibers with different types of metal oxides

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2017, 24(1), pp.82-89
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General

Faten Ermala Che Othman 1 Norhaniza Yusof 1 Hasrinah Hasbullah 1 Juhana Jaafar 1 Ahmad Fauzi Ismail 1 Noor Shawal Nasri 1

1Universiti Teknologi Malaysia

Accredited

ABSTRACT

In this study, composite PAN-based ACNFs embedded with MgO and MnO2 were prepared by the electrospinning method. The resultant pristine ACNFs, ACNF/MgO and ACNF/MnO2 were characterized in terms of their morphological changes, SSA, crystallinity and functional group with FESEM-EDX, the BET method, XRD and FTIR analysis, respectively. Results from this study showed that the SSA of the ACNF/MgO composite (1893 m2 g–1) is significantly higher than that of the pristine ACNFs and ACNF/MnO2 which is 478 and 430 m2 g–1, respectively. FTIR analysis showed peaks of 476 and 547 cm–1, indicating the presence of MgO and MnO2, respectively. The FESEM micrographs analysis showed a smooth but coarser structure in all the ACNFs. Meanwhile, the ACNF/MgO has the smallest fiber diameter (314.38±62.42 nm) compared to other ACNFs. The presence of MgO and MnO2 inside the ACNFs was also confirmed with EDX analysis as well as XRD. The adsorption capacities of each ACNF toward CH4 were tested with the volumetric adsorption method in which the ACNF/MgO exhibited the highest CH4 adsorption up to 2.39 mmol g–1. Meanwhile, allthe ACNF samples followed the pseudo-second order kinetic model with a R2 up to 0.9996.

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2023-07-14)

Total Citation Counts(KCI+WOS) (13) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (14) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

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