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Carbon molecular sieves from soybean straw-based activated carbon for CO2/CH4 separation

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2018, 25(1), pp.68-77
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General

Yuxian Xu 1 Xiaochuan Chen 1 Dan Wu 1 Yongjin Luo 1 Xinping Liu 1 Qingrong Qian 1 Liren Xiao 1 Qinghua Chen 1

1Fujian Normal University

Accredited

ABSTRACT

Soybean straw (SS)-based activated carbon was employed as a precursor to prepare carbon molecular sieves (CMSs) via chemical vapor deposition (CVD) technique using methane as carbon source. Prior to the CVD process, SS was activated by 0.5 wt% ZnCl2, followed by a carbonization at 500°C for 1 h in N2 atmosphere. N2 (77 K) adsorption-desorption and CO2 (273 K) adsorption tests were carried out to analyze the pore structure of the prepared CMSs. The results show that increasing the deposition temperature, time or methane flow rate leads the decrease in N2 adsorption capacity, micropore volume and average pore diameter of CMSs. The adsorption selectivity coefficient of CO2/CH4 achieves as high as 20.8 over CMSs obtained under the methane flow rate of 30 mL min–1 at 800°C for 70 min. The study demonstrates the prepared CMSs are a candidate adsorbent for CO2/CH4 separation.

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2023-07-14)

Total Citation Counts(KCI+WOS) (10) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (10) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

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