One‑ and two‑dimensional carbon nanomaterials as adsorbents of cationic and anionic dyes from aqueous solutions

E. E. Pérez‑Ramírez; M. de la Luz-Asunción; A. L. Martínez-Hernández; G. de la Rosa-Álvarez; S. Fernández-Tavizón; P. Salas; C. Velasco-Santos

doi:10.1007/s42823-019-00029-9

One‑ and two‑dimensional carbon nanomaterials as adsorbents of cationic and anionic dyes from aqueous solutions

Carbon Letters
Abbr : Carbon Lett.
2019, 29(2), pp.155-166
DOI : 10.1007/s42823-019-00029-9
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : February 16, 2018
Accepted : April 8, 2019
Published : April 1, 2019

E. E. Pérez‑Ramírez ¹, M. de la Luz-Asunción ¹, A. L. Martínez-Hernández ¹, G. de la Rosa-Álvarez ², S. Fernández-Tavizón ³, P. Salas ⁴, C. Velasco-Santos ²

¹Tecnológico Nacional de México/Tecnológico de Querétaro
²División de Ciencias Naturales y Exactas, Departamento de Ingeniería Química
³Laboratorio Nacional de Materiales Grafénicos, Centro de Investigación en Química Aplicada
⁴Universidad Nacional Autónoma de México

Accredited

ABSTRACT

One- and two-dimensional carbon nanomaterials were tested as adsorbents for the elimination of two anionic dyes, reactive red 2 and methyl orange, and the cationic dye methylene blue from aqueous solutions under the same conditions. Carbon nanomaterials performed well in the removal of dyes. Surface oxygenated groups in the nanomaterials improved the cationic dyes’ adsorption, but not the adsorption of the anionic dye. The interactions between nanomaterials and dyes were verified by infrared and Raman spectroscopy. The pseudo-second order kinetic model was better fitted to the kinetic experimental data than the Elovich and pseudo-first order models. The equilibrium adsorption data were best fitted by the Langmuir model. The dimensions and morphology of the carbon nanomaterials play an important role in the adsorption of the three dyes. The main mechanism of adsorption of anionic dyes is by the interactions of the aromatic rings of the dye structures and π delocalized electrons on carbon nanostructures; the adsorption of cationic dye is mainly due to electrostatic interactions.

KEYWORDS

Adsorption · Carbon nanomaterials · Dye removal · Pseudo second order · Langmuir model

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 4.82

One‑ and two‑dimensional carbon nanomaterials as adsorbents of cationic and anionic dyes from aqueous solutions

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Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2023-07-14)

Total Citation Counts(KCI+WOS) (10) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (11) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 4.82

One‑ and two‑dimensional carbon nanomaterials as adsorbents of cationic and anionic dyes from aqueous solutions

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KCI Citation Counts (2)

WoS Citation Counts (8) This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2023-07-14)

Total Citation Counts(KCI+WOS) (10) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (11) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

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