Structural, chemical and electronic differences between bare and nitrogen-doped carbon nanoparticles

Lee H. L.; Woon K. L.; Tan Shau Hwai; Wong W. S.; Ariffin A.; Chanlek N.; Nakajima H.; Saisopa T.; Songsiriritthigul P.

doi:10.1007/s42823-019-00014-2

Structural, chemical and electronic differences between bare and nitrogen-doped carbon nanoparticles

Carbon Letters
Abbr : Carbon Lett.
2019, 29(3), pp.255-262
DOI : 10.1007/s42823-019-00014-2
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : May 28, 2018
Accepted : January 20, 2019
Published : June 1, 2019

Lee H. L. ¹, Woon K. L. ¹, Tan Shau Hwai ¹, Wong W. S. ¹, Ariffin A. ¹, Chanlek N. ¹, Nakajima H. ², Saisopa T. ², Songsiriritthigul P. ³

¹Universiti Sains Malaysia
²Synchrotron Light Research Institute
³University of Technology

Accredited

ABSTRACT

Comparisons between bare carbon (CPs) and nitrogen-doped carbon nanoparticles (N-CPs) synthesised using hydrothermal reaction are carried out. It was found that hydrothermal reaction of citric acid yields graphene-like sheets, while the nitrogen doping using ethylenediamine resulted in amorphous polymeric ball-like hydrocarbons devoid of any aromatic rings. Although the Fourier transform infrared spectroscopy, Raman spectroscopy and nuclear magnetic resonance spectroscopy indicate the presence of carbon–carbon double bonds (C=C), and the ground states of both materials are very deep (> 7.8 eV) as measured by ultraviolet photoelectron spectroscopy. This indicates the conjugation is very short. This is supported by the fact that both materials are UV blue emitting peaking at 375 nm probably originating from C=C.

KEYWORDS

Carbon NMR Raman SEM Doping FTIR XRD

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Structural, chemical and electronic differences between bare and nitrogen-doped carbon nanoparticles

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This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-28)

Total Citation Counts(KCI+WOS) (6) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (6) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Structural, chemical and electronic differences between bare and nitrogen-doped carbon nanoparticles

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WoS Citation Counts (5) This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-28)

Total Citation Counts(KCI+WOS) (6) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (6) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

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