Heteroatoms in situ-doped hierarchical porous hollow-activated carbons for high-performance supercapacitor

Yan Rui; Wang Kai; Tian Xiaodong; Li Xiao; Yang Tao; Xu Xiaotong; He Yiting; Lei Shiwen; Song Yan

doi:10.1007/s42823-019-00102-3

Heteroatoms in situ-doped hierarchical porous hollow-activated carbons for high-performance supercapacitor

Carbon Letters
Abbr : Carbon Lett.
2020, 30(3), pp.331-344
DOI : 10.1007/s42823-019-00102-3
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : July 8, 2019
Accepted : October 17, 2019
Published : June 1, 2020

Yan Rui ¹, Wang Kai ², Tian Xiaodong ³, Li Xiao ⁴, Yang Tao ³, Xu Xiaotong ⁴, He Yiting ⁴, Lei Shiwen ⁴, Song Yan ⁴

¹Taiyuan Institute of Technolog
²Shanxi Coal Import and Export Group Co
³Chinese Academy of Sciences
⁴Chinese Academy of Sciences

Accredited

ABSTRACT

Heteroatoms in situ-doped hierarchical porous hollow-activated carbons (HPHACs) have been prepared innovatively by pyrolyzation of setaria viridis combined with alkaline activation for the frst time. The micro-morphology, pore structure, chemical compositions, and electrochemical properties are researched in detail. The obtained HPHACs are served as outstand�ing electrode materials in electrochemical energy storage ascribe to the particular hierarchical porous and hollow structure, and the precursor setaria viridis is advantage of eco-friendly as well as cost-efective. Electrochemical measurement results of the HPHACs electrodes exhibit not only high specifc capacitance of 350 F g−1 at 0.2 A g−1, and impressive surface specifc capacitance (Cs) of 49.9 μF cm−2, but also substantial rate capability of 68% retention (238 F g−1 at 10 A g−1) and good cycle stability with 99% retention over 5000 cycles at 5 A g−1 in 6 M KOH. Besides, the symmetrical supercapacitor device based on the HPHACs electrodes exhibits excellent energy density of 49.5 Wh kg−1 at power density of 175 W kg−1 , but still maintains favorable energy density of 32.0 Wh kg−1 at current density of 1 A g−1 in 1-ethy-3-methylimidazolium tetrafuoroborate (EMIMBF4) ionic liquid electrolyte, and the excellent cycle stability behaviour shows the nearly 97% ratio capacitance retention of the initial capacitance after 10,000 cycles at current density of 2 A g−1. Overall, the results indicate that HPHACs derived from setaria viridis have appealing electrochemical performances thus are promising electrode materi�als for supercapacitor devices and large-scale applications.

KEYWORDS

Hierarchical porous hollow-activated carbons · Setaria viridis · Supercapacitor · Energy storage · High energy density

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[journal] Dutta S / 2014 / Hierarchically porous carbon derived from polymers and biomass : effect of interconnected pores on energy applications / Energy Environ Sci 7 : 3574~

[journal] Wang G / 2012 / A review of electrode materials for electrochemical supercapacitors / Chem Soc Rev 41 : 797~

[journal] Zhang Q / 2013 / Nanomaterials for energy conversion and storage / Chem Soc Rev 42 : 3127~

[journal] Yan J / 2014 / Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities / Adv Energy Mater 4 : 1~

[journal] Yu G / 2013 / Hybrid nanostructured materials for high-performance electrochemical capacitors / Nano Energy 2 : 213~

[journal] Zhang J / 2016 / Carbon science in 2016 : status, challenges and perspectives / Carbon 98 : 708~

[journal] Zhai Y / 2011 / Carbon materials for chemical capacitive energy storage / Adv Mater 23 : 4828~

[journal] Qu D / 1998 / Studies of activated carbons used in doublelayer capacitors / J Power Sources 74 : 99~

[journal] Jiang H / 2013 / 3D carbon based nanostructures for advanced supercapacitors / Energy Environ Sci 6 : 41~

[journal] Jain A / 2016 / Hydrothermal conversion of biomass waste to activated carbon with high porosity : a review / Chem Eng J 283 : 789~

[journal] Wang C / 2018 / Biomass derived nitrogen-doped hierarchical porous carbon sheets for supercapacitors with high performance / J Colloid Interf Sci 523 : 133~

[journal] Peng C / 2013 / Promising activated carbons derived from waste tea-leaves and their application in high performance supercapacitors electrodes / Electrochim Acta 87 : 401~

[journal] Li X / 2011 / Preparation of capacitor’s electrode from sunflower seed shell / Bioresour Technol 102 : 1118~

[journal] Mi J / 2012 / Coconut-shellbased porous carbons with a tunable micro/mesopore ratio for high-performance supercapacitors / Energy Fuels 26 : 5321~

[journal] Sun L / 2013 / From coconut shell to porous graphene-like nanosheets for high-power supercapacitors / J Mater Chem A 1 : 6462~

[journal] Choi WS / 2012 / Effect of ball milling on electrochemical characteristics of walnut shell-based carbon electrodes for EDLCs / Microporous Mesoporous Mater 155 : 274~

[journal] Elmouwahidi A / 2012 / Activated carbons from KOH-activation of argan(Argania spinosa)seed shells as supercapacitor electrodes / Bioresour Technol 111 : 185~

[journal] Wang K / 2016 / Bio-inspired hollow activated carbon microtubes derived from willow catkins for supercapacitors with high volumetric performance / Mater Lett 174 : 249~

[journal] Wang K / 2017 / High capacitive performance of hollow activated carbon fibers derived from willow catkins / Appl Surf Sci 394 : 569~

[journal] Wang K / 2015 / Promising biomass-based activated carbons derived from willow catkins for high performance supercapacitors / Electrochim Acta 166 : 1~

[journal] Rufford TE / 2010 / Microstructure and electrochemical double-layer capacitance of carbon electrodes prepared by zinc chloride activation of sugar cane bagasse / J Power Sources 195 : 912~

[journal] Chen W / 2010 / A fish scale based hierarchical lamellar porous carbon material obtained using a natural template for high performance electrochemical capacitors / J Mater Chem 20 : 4773~

[journal] Huang W / 2011 / Hierarchical porous carbon obtained from animal bone and evaluation in electric double-layer capacitors / Carbon 49 : 838~

[journal] Zhi L / 2012 / Carbonized chicken eggshell membranes with 3D architectures as high-performance electrode materials for supercapacitors / Adv Energy Mater 2 : 431~

[journal] Raymundo-Piñero E / 2006 / A high-performance carbon for supercapacitors obtained by carbonization of a seaweed biopolymer / Adv Mater 18 : 1877~

[journal] Liu C / 2010 / Graphene-based supercapacitor with an ultrahigh energy density / Nano Lett 10 : 4863~

[journal] Li B / 2016 / Nitrogen-doped activated carbon for a high energy hybrid supercapacitor / Energy Environ Sci 9 : 102~

[journal] Tian X / 2017 / Flexible carbon nanofiber mats with improved graphitic structure as scaffolds for efficient all-solid-state supercapacitor / Electrochim Acta 247 : 1060~

[journal] Tian X / 2018 / Porous worm-like NiMoO4coaxially decorated electrospun carbon nanofiber as binder-free electrodes for high performance supercapacitors and lithium-ion batteries / Appl Surf Sci 434 : 49~

[journal] Wang R / 2012 / Promising porous carbon derived from celtuce leaves with outstanding supercapacitance and CO2capture performance / ACS Appl Mater Interf 4 : 5800~

[journal] Biswal M / 2013 / From dead leaves to high energy density supercapacitors / Energy Environ Sci 6 : 1249~

[journal] Hou J / 2015 / Hierarchical porous nitrogen-doped carbon nanosheets derived from silk for ultrahighcapacity battery anodes and supercapacitors / ACS Nano 9 : 2556~

[journal] Orfão JJM / 1999 / Pyrolysis kinetics of lignocellulosic materials-three independent reactions model / Fuel 78 : 349~

[journal] Tsamba AJ / 2006 / Pyrolysis characteristics and global kinetics of coconut and cashew nut shells / Fuel Process Technol 87 : 523~

[journal] Liu Y / 2015 / Preparation of low density hollow carbon fibers by bi-component gel-spinning method / J Mater Sci 50 : 3614~

[journal] Guan T / 2017 / Template-free preparation of layer-stacked hierarchical porous carbons from coal tar pitch for high performance all-solid-state supercapacitors / J Mater Chem A 5 : 15869~

[journal] Guo Y / 2014 / Hierarchical porous carbon derived from sulfonated pitch for electrical double layer capacitors / J Power Sources 252 : 235~

[journal] Zheng Z / 2011 / Hierarchical porous carbons prepared by an easy one-step carbonization and activation of phenol–formaldehyde resins with high performance for supercapacitors / J Power Sources 196 : 1615~

[journal] Wang J / 2012 / KOH activation of carbon-based materials for energy storage / J Mater Chem 22 : 23710~

[journal] Lillo-Ródenas MA / 2003 / Understanding chemical reactions between carbons and NaOH and KOH : an insight into the chemical activation mechanism / Carbon 41 : 267~

[journal] Zolyomi VKJ / 2011 / Resonance raman spectroscopy of graphite and graphene / Phys Status Solidi-b 248 : 2435~

[journal] Qian W / 2014 / Human hair-derived carbon flakes for electrochemical supercapacitors / Energy Environ Sci 7 : 379~

[journal] Wang C / 2017 / Three-dimensional framework of graphene nanomeshes shell/Co3O4 synthesized as superior bifunctional electrocatalyst for Zinc-Air batteries / ACS Appl Mater Interf 9 : 41273~

[journal] Chen J / 2016 / Nitrogen-doped hierarchically porous carbon foam : a free-standing electrode and mechanical support for high-performance supercapacitors / Nano Energy 25 : 193~

[journal] Chen Y / 2018 / Nitrogen and sulfur co-doped porous graphene aerogel as an efficient electrode material for high performance supercapacitor in ionic liquid electrolyte / J Power Sour 390 : 215~

[journal] Tian X / 2015 / Synthesis of nitrogen-doped electrospun carbon nanofibers with superior performance as efficient supercapacitor electrodes in alkaline solution / Electrochim Acta 185 : 40~

[journal] Hulicova-Jurcakova D / 2009 / Combined effect of nitrogen-and oxygen-containing functional groups of microporous activated carbon on its electrochemical performance in supercapacitors / Adv Funct Mater 19 : 438~

[journal] Zhao L / 2010 / Nitrogen-containing hydrothermal carbons with superior performance in supercapacitors / Adv Mater 22 : 5202~

[journal] Song S / 2015 / Facile selftemplating large scale preparation of biomass-derived 3D hierarchical porous carbon for advanced supercapacitors / J Mater Chem A 3 : 18154~

[journal] White RJ / 2009 / Tuneable porous carbonaceous materials from renewable resources / Chem Soc Rev 38 : 3401~

[journal] Zhai D / 2010 / Preparation of mesophase-pitch-based activated carbons for electric double layer capacitors with high energy density / Microporous Mesoporous Mater 130 : 224~

[journal] Sun G / 2012 / Preparation of mesoporous carbon spheres with a bimodal pore size distribution and its application for electrochemical double layer capacitors based on ionic liquid as the electrolyte / Microporous Mesoporous Mater 151 : 282~

[journal] Zhou J / 2011 / Capacitive performance of ordered mesoporous carbons with tunable porous texture in ionic liquid electrolytes / Solid State Sci 13 : 2000~

[journal] Zhou D / 2017 / High energy supercapacitors based on interconnected porous carbon nanosheets with ionic liquid electrolyte / Microporous Mesoporous Mater 241 : 202~

[journal] Tee E / 2016 / Supercapacitors based on activated silicon carbide-derived carbon materials and ionic liquid / J Electrochem Soc 163 : A1317~

[journal] Pandey GP / 2016 / Thermostable gel polymer electrolyte based on succinonitrile and ionic liquid for high-performance solid-state supercapacitors / J Power Sources 328 : 510~

[journal] Shen B / 2016 / Carbon encapsulated RuO2nano-dots anchoring on graphene as an electrode for asymmetric supercapacitors with ultralong cycle life in an ionic liquid electrolyte / J Mater Chem A 4 : 8180~

[journal] Zhang X / 2015 / A flexible ionic liquid gelled PVA-Li2SO4 polymer electrolyte for semi-solid-state supercapacitors / Adv Mater Interf 2 : 1500267~

[journal] Shaikh JS / 2018 / Symmetric supercapacitor : sulphurized graphene and ionic liquid / J Colloid Interf Sci 527 : 40~

[journal] He X / 2013 / Efficient preparation of biomass-based mesoporous carbons for supercapacitors with both high energy density and high power density / J Power Sources 240 : 109~

[journal] Zou Z / 2018 / Highly mesoporous carbon flakes derived from a tubular biomass for high power electrochemical energy storage in organic electrolyte / Mater Chem Phys

[journal] Sun J / 2018 / Biomass-derived nitrogen-doped porous carbons with tailared hierarchical porosity and high specific surface area for high energy and power density supercapacitors / Appl Surf Sci 427 : 807~

[journal] Yun YS / 2015 / Hierarchically porous carbon nanosheets from waste coffee grounds for supercapacitors / ACS Appl Mater Interfaces 7 : 3684~

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Heteroatoms in situ-doped hierarchical porous hollow-activated carbons for high-performance supercapacitor

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Scopus Citation Counts (18) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Heteroatoms in situ-doped hierarchical porous hollow-activated carbons for high-performance supercapacitor

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Total Citation Counts(KCI+WOS) (19) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (18) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

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