@article{ART002695595},
author={Che Othman Faten Ermala and Ismail Mohd Shafri and Yusof Norhaniza and Samitsu Sadaki and Yusop Mohd Zamri and Tajul Arifin Nur Fatihah and Alias Nur Hashimah and Jaafar Juhana and Aziz Farhana and Wan Salleh Wan Norharyati and Ismail Ahmad Fauzi},
title={Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures},
journal={Carbon Letters},
issn={1976-4251},
year={2020},
volume={30},
number={5},
pages={535-543},
doi={10.1007/s42823-020-00123-3}
TY - JOUR
AU - Che Othman Faten Ermala
AU - Ismail Mohd Shafri
AU - Yusof Norhaniza
AU - Samitsu Sadaki
AU - Yusop Mohd Zamri
AU - Tajul Arifin Nur Fatihah
AU - Alias Nur Hashimah
AU - Jaafar Juhana
AU - Aziz Farhana
AU - Wan Salleh Wan Norharyati
AU - Ismail Ahmad Fauzi
TI - Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures
JO - Carbon Letters
PY - 2020
VL - 30
IS - 5
PB - Korean Carbon Society
SP - 535
EP - 543
SN - 1976-4251
AB - The present work focused on the determination of texture, morphology, crystallinity, and gas adsorption characteristics of porous graphene prepared from rice husks ashes at diferent stabilization temperature. The stabilization temperature applied in this work is 100 °C, 200 °C, 300 °C, and 400 °C to convert rice husk into rice husk ashes (RHA). Chemical activation was adopted at temperature 800 °C using potassium hydroxide (KOH) as dehydrating agent at (1:5) impregnation ratio to convert RHA into rice husk ashes-derived graphene (GRHA). The resultant GRHA were characterized in terms of their morphologi�cal changes, SSA, crystallinity, and functional group with TEM, the BET method, Raman spectroscopy, and XRD analysis, respectively. Results from this study showed that the SSA of the GRHA at stabilization temperature 200 °C (1556.3 m2 /g) is the highest compared to the other stabilization temperature. Raman spectroscopy analysis revealed that all GRHA samples possess D, G, and 2D bands, which confrm the successful synthesis of the rice husks into porous graphene-like materials, known as GRHA. Appearance of difraction peak in XRD at 44.7° indicating the graphitic structure of all the GRHA sam�ples. Meanwhile, the TEM images of GRHA200 exhibited wrinkled structures due to the intercalation of oxygen and a few layers of graphene fakes. These wrinkled structures and graphene layers are the other factors that lead to the highest SSA of GRHA200 compared to other prepared samples GRHA. Furthermore, the adsorption capacity of CH4 for GRHA200 is up to 43 cm3 /g at 35 bar and ambient temperature, almost double the adsorption capacity performance of GRHA400 at the same operating pressure and temperature.
KW - Rice husk ashes-derived graphene · Porous adsorbent · Graphene-like materials · Specifc surface area · Microporous · Stabilization
DO - 10.1007/s42823-020-00123-3
ER -
Che Othman Faten Ermala, Ismail Mohd Shafri, Yusof Norhaniza, Samitsu Sadaki, Yusop Mohd Zamri, Tajul Arifin Nur Fatihah, Alias Nur Hashimah, Jaafar Juhana, Aziz Farhana, Wan Salleh Wan Norharyati and Ismail Ahmad Fauzi. (2020). Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures. Carbon Letters, 30(5), 535-543.
Che Othman Faten Ermala, Ismail Mohd Shafri, Yusof Norhaniza, Samitsu Sadaki, Yusop Mohd Zamri, Tajul Arifin Nur Fatihah, Alias Nur Hashimah, Jaafar Juhana, Aziz Farhana, Wan Salleh Wan Norharyati and Ismail Ahmad Fauzi. 2020, "Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures", Carbon Letters, vol.30, no.5 pp.535-543. Available from: doi:10.1007/s42823-020-00123-3
Che Othman Faten Ermala, Ismail Mohd Shafri, Yusof Norhaniza, Samitsu Sadaki, Yusop Mohd Zamri, Tajul Arifin Nur Fatihah, Alias Nur Hashimah, Jaafar Juhana, Aziz Farhana, Wan Salleh Wan Norharyati, Ismail Ahmad Fauzi "Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures" Carbon Letters 30.5 pp.535-543 (2020) : 535.
Che Othman Faten Ermala, Ismail Mohd Shafri, Yusof Norhaniza, Samitsu Sadaki, Yusop Mohd Zamri, Tajul Arifin Nur Fatihah, Alias Nur Hashimah, Jaafar Juhana, Aziz Farhana, Wan Salleh Wan Norharyati, Ismail Ahmad Fauzi. Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures. 2020; 30(5), 535-543. Available from: doi:10.1007/s42823-020-00123-3
Che Othman Faten Ermala, Ismail Mohd Shafri, Yusof Norhaniza, Samitsu Sadaki, Yusop Mohd Zamri, Tajul Arifin Nur Fatihah, Alias Nur Hashimah, Jaafar Juhana, Aziz Farhana, Wan Salleh Wan Norharyati and Ismail Ahmad Fauzi. "Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures" Carbon Letters 30, no.5 (2020) : 535-543.doi: 10.1007/s42823-020-00123-3
Che Othman Faten Ermala; Ismail Mohd Shafri; Yusof Norhaniza; Samitsu Sadaki; Yusop Mohd Zamri; Tajul Arifin Nur Fatihah; Alias Nur Hashimah; Jaafar Juhana; Aziz Farhana; Wan Salleh Wan Norharyati; Ismail Ahmad Fauzi. Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures. Carbon Letters, 30(5), 535-543. doi: 10.1007/s42823-020-00123-3
Che Othman Faten Ermala; Ismail Mohd Shafri; Yusof Norhaniza; Samitsu Sadaki; Yusop Mohd Zamri; Tajul Arifin Nur Fatihah; Alias Nur Hashimah; Jaafar Juhana; Aziz Farhana; Wan Salleh Wan Norharyati; Ismail Ahmad Fauzi. Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures. Carbon Letters. 2020; 30(5) 535-543. doi: 10.1007/s42823-020-00123-3
Che Othman Faten Ermala, Ismail Mohd Shafri, Yusof Norhaniza, Samitsu Sadaki, Yusop Mohd Zamri, Tajul Arifin Nur Fatihah, Alias Nur Hashimah, Jaafar Juhana, Aziz Farhana, Wan Salleh Wan Norharyati, Ismail Ahmad Fauzi. Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures. 2020; 30(5), 535-543. Available from: doi:10.1007/s42823-020-00123-3
Che Othman Faten Ermala, Ismail Mohd Shafri, Yusof Norhaniza, Samitsu Sadaki, Yusop Mohd Zamri, Tajul Arifin Nur Fatihah, Alias Nur Hashimah, Jaafar Juhana, Aziz Farhana, Wan Salleh Wan Norharyati and Ismail Ahmad Fauzi. "Methane adsorption by porous graphene derived from rice husk ashes under various stabilization temperatures" Carbon Letters 30, no.5 (2020) : 535-543.doi: 10.1007/s42823-020-00123-3