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Oriented wrinkle textures of free-standing graphene nanosheets: application as a high-performance lithium-ion battery anode

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2021, 31(2), pp.277-285
  • DOI : 10.1007/s42823-020-00163-9
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : January 28, 2020
  • Accepted : June 17, 2020
  • Published : April 1, 2021

Jeong Hee-Sung 1 Kim Jongsoon 2 Jo Kyoung-Il 3 KEE JIN HO 4 Choi, Jae-Hak 4 Koo Jaseung 1

1충남대학교 유기재료공학과
2세종대학교 나노신소재공학과
3한국원자력연구원
4충남대학교

Accredited

ABSTRACT

Morphology control of a graphene nanosheet (GNS) is important for graphene-based battery electrodes to exhibit the increased practical surface area and the enhanced ion diffusion into the nanosheets. Nevertheless, it is very difficult to minutely control the shape of graphene nanosheets based on the conventional GNS suspension methods. In this work, we fabricated wrinkle textures of free-standing GNS for large area using Langmuir–Schaefer technique. The wrinkles are oriented vertically to the direction of the monolayer compression. The textured structure of GNS was obtained by cross-deposition of each layer with controlling the orientation of the wrinkle direction. These wrinkles can cause Li-ion to diffuse into the voids created by them and raise the specific surface area between the GNSs. Consequently, as a prospective anode for Li-ion battery, the wrinkled GNS multilayer, exhibits the high specific capacity of ~ 740 mAh g−1 at 100 mA g−1 and the great power capability with ~ 404 mAh g−1 being delivered even at 2 A g−1. Furthermore, outstanding cycle performance of the wrinkled GNS multilayer is achieved over 200 cycles at 300 mA g−1 with high Coulombic efficiency of ~ 96%.

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-27)

Total Citation Counts(KCI+WOS) (13) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (13) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

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