Nitrogen-doped and hierarchically porous carbon derived from spent coffee ground for efficient adsorption of organic dyes

Dai Zhong; Ren Peng-Gang; Zhang Hua; Gao Xin; Jin Yan-Ling

doi:10.1007/s42823-021-00248-z

Nitrogen-doped and hierarchically porous carbon derived from spent coffee ground for efficient adsorption of organic dyes

Carbon Letters
Abbr : Carbon Lett.
2021, 31(6), pp.1249-1260
DOI : 10.1007/s42823-021-00248-z
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : November 2, 2020
Accepted : April 12, 2021
Published : December 1, 2021

Dai Zhong ¹, Ren Peng-Gang ¹, Zhang Hua ¹, Gao Xin ¹, Jin Yan-Ling ¹

¹Xi’an University of Technology

Accredited

ABSTRACT

Here, a novel nitrogen-doped carbon nano-material (N-CGNM) with hierarchically porous structure was prepared from spent cofee ground for efcient adsorption of organic dyes by a simple one-step carbonization process (the uniform mixture consists of spent cofee ground, urea, and CaCl2 with the ratio of 1:1:1, which was heated to 1000 °C with a rate of 10 °C min−1 and held at 1000 °C for 90 min in N2 atmosphere to carry out carbonization, activation, and N-doping concurrently). The morphology and structure analysis show that the prepared N-CGNM exhibits hierarchical pore structure, high specifc surface area (544 m2 /g), and large numbers of positively charged nitrogen-containing groups. This unique structure and chemical composition endow N-CGNM with an excellent adsorption capacity toward anion Congo red (623.12±21.69 mg/g), which is obviously superior to that (216.47±18.43 mg/g) of untreated spent cofee ground-based carbon nano-materials (CGM). Oppositely, the adsorption capacity of N-CGNM towards cation methylene blue is inferior to that of CGM due to the existence of electrostatic repulsion. These fndings show a great guidance for the development of low-cost but efcient selective adsorbent.

KEYWORDS

Nitrogen-doped · Adsorption · Spent cofee ground · One-step carbonization · Organic dyes

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Total Citation Counts(KCI+WOS) (14) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (14) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

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[journal] Ali H / 2010 / Biodegradation of Synthetic Dyes—A Review / Water Air Soil Pollut 213 : 251~273

[journal] Khaled A / 2009 / Removal of Direct N Blue-106 from artificial textile dye effluent using activated carbon from orange peel : adsorption isotherm and kinetic studies / J Hazard Mater 165 : 100~110

[journal] Qu X / 2013 / Applications of nanotechnology in water and wastewater treatment / Water Res 47 : 3931~3946

[journal] Tang R / 2020 / Organoarsenic feed additives in biological wastewater treatment processes : removal, biotransformation, and associated impacts / J Hazard Mater 406 : 124789~

[journal] El-Gohary F / 2009 / Decolorization and COD reduction of disperse and reactive dyes wastewater using chemicalcoagulation followed by sequential batch reactor(SBR)process / Desalination 249 : 1159~1164

[journal] Wu T / 2011 / Adsorption characteristics of acrylonitrile, p-toluenesulfonic acid, 1-naphthalenesulfonic acid and methyl blue on graphene in aqueous solutions / Chem Eng J 173 : 144~149

[journal] Wong S / 2018 / Recent advances in applications of activated carbon from bio-waste for wastewater treatment : a short review / J Clean Prod 175 : 361~375

[journal] Dong Z / 2014 / Bio-inspired surface-functionalization of graphene oxide for the adsorption of organic dyes and heavy metal ions with a superhigh capacity / Journal of Materials Chemistry A 2 : 5034~5040

[journal] Yi FY / 2015 / Polyoxometalates-based heterometallic organic-inorganic hybrid materials for rapid adsorption and selective separation of methylene blue from aqueous solutions / Chem Commun 51 : 3336~3339

[journal] Yagub MT / 2014 / Dye and its removal from aqueous solution by adsorption : a review / Adv Coll Interface Sci 209 : 172~184

[journal] Dai Y / 2019 / The adsorption, regeneration and engineering applications of biochar for removal organic pollutants : a review / Chemosphere 223 : 12~27

[journal] Menya E / 2018 / Production and performance of activated carbon from rice husks for removal of natural organic matter from water : a review / Chem Eng Res Des 129 : 271~296

[journal] Yusuf M / 2015 / Applications of graphene and its derivatives as an adsorbent for heavy metal and dye removal : a systematic and comprehensive overview / RSC Adv 5 : 50392~50420

[journal] Jain A / 2016 / Hydrothermal conversion of biomass waste to activated carbon with high porosity : a review / Chem Eng J 283 : 789~805

[journal] Bhatnagar A / 2015 / Agricultural waste peels as versatile biomass for water purification—a review / Chem Eng J 270 : 244~271

[journal] Arias JO / 2020 / New powder material obtained from spent coffee ground and whey protein; Thermal and morphological analysis / Mater Chem Phys 240 : 122171~

[journal] Cloete KJ / 2019 / Physico-elemental analysis of roasted organic coffee beans from Ethiopia, Colombia, Honduras, and Mexico using X-ray micro-computed tomography and external beam particle induced X-ray emission / Food Chem 2 : 100032~

[journal] Nguyen VT / 2019 / Influence of pyrolysis temperature on polycyclic aromatic hydrocarbons production and tetracycline adsorption behavior of biochar derived from spent coffee ground / Biores Technol 284 : 197~203

[journal] Yahya MA / 2015 / Agricultural biowaste materials as potential sustainable precursors used for activated carbon production : a review / Renew Sustain Energy Rev 46 : 218~235

[journal] Chen Y / 2011 / Application studies of activated carbon derived from rice husks produced by chemical-thermal process—a review / Adv Coll Interface Sci 163 : 39~52

[journal] Liou TH / 2010 / Development of mesoporous structure and high adsorption capacity of biomass-based activated carbon by phosphoric acid and zinc chloride activation / Chem Eng J 158 : 129~142

[journal] Williams PT / 2004 / High grade activated carbon matting derived from the chemical activation and pyrolysis of natural fibre textile waste / J Anal Appl Pyrol 71 : 971~986

[journal] Kundu A / 2019 / Kinetics, isotherm, and thermodynamic studies of methylene blue selective adsorption and photocatalysis of malachite green from aqueous solution using layered Na-intercalated Cu-doped Titania / Appl Clay Sci 183 : 105323~

[journal] Li M / 2020 / Porphyrin-based porous organic polymer, Py-POP, as a multifunctional platform for efficient selective adsorption and photocatalytic degradation of cationic dyes / Microporous Mesoporous Mater 292 : 109774~

[journal] Lin R / 2019 / Selective and enhanced adsorption of the monosubstituted benzenes on the Fe-modified MCM-41 : contribution of the substituent groups / Chemosphere 237 : 124546~

[journal] Wang W / 2014 / Self-healing properties of protective coatings containing isophorone diisocyanate microcapsules on carbon steel surfaces / Corros Sci 80 : 528~535

[journal] Allan D / 2019 / Oxidative and non-oxidative degradation of a TDI-based polyurethane foam : Volatile product and condensed phase characterisation by FTIR and solid state 13C NMR spectroscopy / Polym Degrad Stab 161 : 57~73

[journal] Ou Y / 2018 / Investigation on the thermal decomposition of hydroxyl terminated polyether based polyurethanes with inert and energetic plasticizers by DSC-TG-MS-FTIR / J Anal Appl Pyrol 132 : 94~101

[journal] Zhao G / 2018 / One-step production of O-N-S co-doped three-dimensional hierarchical porous carbons for high-performance supercapacitors / Nano Energy 47 : 547~555

[journal] Peng H / 2016 / Nitrogendoped interconnected carbon nanosheets from pomelo mesocarps for high performance supercapacitors / Electrochim Acta 190 : 862~871

[journal] Li Y / 2016 / Nitrogen and sulfur co-doped porous carbon nanosheets derived from willow catkin for supercapacitors / Nano Energy 19 : 165~175

[journal] Puziy AM / 2008 / XPS and NMR studies of phosphoric acid activated carbons / Carbon 46 : 2113~2123

[journal] Mungse HP / 2019 / Alkylated graphene oxide and reduced graphene oxide : Grafting density, dispersion stability to enhancement of lubrication properties / J Colloid Interface Sci 541 : 150~162

[journal] Chen Y / 2018 / Nitrogen and sulfur co-doped porous graphene aerogel as an efficient electrode material for high performance supercapacitor in ionic liquid electrolyte / J Power Sources 390 : 215~223

[journal] Wang N / 2019 / Partly nitrogenized nickel oxide hollow spheres with multiple compositions for remarkable electrochemical performance / Chem Eng J 358 : 531~539

[journal] Xin G / 2018 / Preparation of high-capacitance N, S co-doped carbon nanospheres with hierarchical pores as supercapacitors / Electrochim Acta 291 : 168~176

[journal] Dai Z / 2019 / Nitrogen-sulphur Co-doped graphenes modified electrospun lignin/polyacrylonitrile-based carbon nanofiber as high performance supercapacitor / J Power Sources 437 : 226937~

[journal] Dai Z / 2018 / High-strength lignin-based carbon fibers via a low-energy method / RSC Adv 8 : 1218~1224

[journal] Chen J / 2018 / Integrated paper electrodes derived from cotton stalks for high-performance flexible supercapacitors / Nano Energy 53 : 337~344

[journal] Yang S / 2019 / Biomass derived interconnected hierarchical micro-meso-macro-porous carbon with ultrahigh capacitance for supercapacitors / Carbon 147 : 540~549

[journal] Su P / 2012 / Mesoporous graphitic carbon nanodisks fabricated via catalytic carbonization of coordination polymers / Chem Commun 48 : 8769~

[journal] Peng H / 2014 / One-step preparation of ultrathin nitrogen-doped carbon nanosheets with ultrahigh pore volume for high-performance supercapacitors / Journal of Materials Chemistry A 2 : 17297~17301

[journal] Tiwari JN / 2013 / Reduced graphene oxide-based hydrogels for the efficient capture of dye pollutants from aqueous solutions / Carbon 56 : 173~182

[journal] Xu J / 2012 / Decontamination of bisphenol a from aqueous solution by graphene adsorption / Langmuir 28 : 8418~8425

[journal] Roy A / 2013 / Equilibrium, kinetic, and thermodynamic studies of azo dye adsorption from aqueoussolution by chemically modified lignocellulosic jute fiber / Ind Eng Chem Res 52 : 6502~6512

[journal] Huang X / 2009 / Hg(II)removal from aqueous solution by bayberry tannin-immobilized collagen fiber / J Hazard Mater 170 : 1141~1148

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 4.82

Nitrogen-doped and hierarchically porous carbon derived from spent coffee ground for efficient adsorption of organic dyes

ABSTRACT

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This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-27)

Total Citation Counts(KCI+WOS) (14) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (14) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 4.82

Nitrogen-doped and hierarchically porous carbon derived from spent coffee ground for efficient adsorption of organic dyes

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WoS Citation Counts (11) This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-27)

Total Citation Counts(KCI+WOS) (14) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (14) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

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