Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04
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pISSN : 1976-4251 / eISSN : 2233-4998
- https://journal.kci.go.kr/carbon
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Hierarchically porous carbon derived from tobacco waste by one-step molten salt carbonization for supercapacitor
- Carbon Letters
- Abbr : Carbon Lett.
- 2022, 32(1), pp.251-263
- DOI : 10.1007/s42823-021-00271-0
- Publisher : Korean Carbon Society
- Research Area : Natural Science > Natural Science General > Other Natural Sciences General
- Received : March 23, 2021
- Accepted : August 2, 2021
- Published : January 1, 2022
Liu Yuxuan 1, Cheng Xinhua 1, Zhang Shenghui 1
1중화인민공화국 은시 후베이민주대학교 화공환경공학과
Accredited
ABSTRACT
High-performance carbon materials were prepared via a one-step molten salt carbonization of tobacco waste used as electrode materials for supercapacitors. Carbon material prepared by carbonization for 3 h in molten CaCl2 at 850 °C exhibits hierarchically porous structure and ideal capacitive behavior. In a three-electrode configuration with 1 mol L−1 H2SO4 aqueous solution, it delivers specific capacitance of 196.5 F g−1 at 0.2 A g−1, energy density of 27.2 Wh kg−1 at 0.2 A g−1, power density of 983.5 W kg−1 at 2 A g−1, and excellent cyclic stability with 94% capacitance retention after 5000 charge–discharge cycles at 1 A g−1. Moreover, in a symmetrical two-electrode configuration with 6 mol L−1 KOH aqueous solution, it delivers specific capacitance of 111.1 F g−1 at 0.2 A g−1, energy density of 3.8 Wh kg−1 at 0.2 A g−1, and power density of 482.0 W kg−1 at 2 A g−1. The relationship between hierarchically porous structure and capacitive performance is also discussed.
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