Carbon-coated SiOx anode materials via PVD and pyrolyzed fuel oil to achieve lithium-ion batteries with high cycling stability

Kim Daesup (김대섭); Kim Kyung Hoon (김경훈); Lim Chaehun; Lee, Young-Seak (이영석)

doi:10.1007/s42823-021-00314-6

Carbon-coated SiOx anode materials via PVD and pyrolyzed fuel oil to achieve lithium-ion batteries with high cycling stability

Carbon Letters
Abbr : Carbon Lett.
2022, 32(1), pp.321-328
DOI : 10.1007/s42823-021-00314-6
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : November 10, 2021
Accepted : December 14, 2021
Published : January 1, 2022

Kim Daesup ¹, Kim Kyung Hoon ¹, Lim Chaehun ¹, Lee, Young-Seak ¹

¹충남대학교

Accredited

ABSTRACT

Silicon oxide (SiOx) has been considered one of the most promising anode materials for lithium-ion batteries due to having a higher capacity than the commercial graphite anodes. However, its practical application is hampered by very large volume variations. In this work, pyrolysis fuel oil is the carbon coating precursor, and physical vapor deposition (PVD) is performed on SiOx at 200 and 400 °C (SiOx@C 200 and SiOx@C 400), followed by carbonization at 950 °C. SiOx@C 200 has a carbon coating layer with a thickness of ~ 20 nm and an amorphous structure, while that of SiOx@C 400 is approximately 10 nm thick and has a more semigraphitic structure. The carbon-coated SiOx anodes display better charge–discharge performance than the pristine SiOx anode. In particular, SiOx@C 200 shows the highest reversible capacity compared with the other samples at high C-rates (2.0 and 5.0 C). Moreover, SiOx@C 200 exhibits excellent cycling stability with a capacity retention of 90.2% after 80 cycles at 1.0 C. This result is ascribed to the suppressed volume expansion by the PFO carbon coating on SiOx after PVD.

KEYWORDS

Silicon oxide, Lithium-ion batteries, PFO, Physical vapor deposition

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Total Citation Counts(KCI+WOS) (15) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (19) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Carbon-coated SiOx anode materials via PVD and pyrolyzed fuel oil to achieve lithium-ion batteries with high cycling stability

ABSTRACT

KEYWORDS

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (15) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (19) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Carbon-coated SiOx anode materials via PVD and pyrolyzed fuel oil to achieve lithium-ion batteries with high cycling stability

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KEYWORDS

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WoS Citation Counts (9) This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (15) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (19) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

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This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

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