본문 바로가기
  • Home

Preparation and properties of self-healing polyurethane based on disulfide and hydrogen bonding

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2023, 33(1), pp.163-175
  • DOI : 10.1007/s42823-022-00413-y
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : July 4, 2022
  • Accepted : September 24, 2022
  • Published : February 1, 2023

Liu Shouxiang 1 Chen Yu 1 Qiao Yang 1 Li Zhiqiang 1 Wei Yanyan 1

1Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-Plastics, School of Polymer Science and Engineering, Qingdao University of Science and Technology

Accredited

ABSTRACT

Cracks are an inevitable problem during the use of materials, and flexible sensors with self-healing capability are of great importance for applications in wearable devices and skin-like electronic devices. This paper prepared self-healing flexible strain sensors by compounding self-healing polyurethane with carbon nanotubes. First, by changing the ratio of disulfide bonds, a good balance between mechanical properties and self-healing efficiency was achieved in the prepared self-healing polyurethane. The most balanced sample reached 12.28 MPa in tensile strength, after 24 h of self-repair at 30 °C, the tensile strength was 7.75 MPa, and the self-repair efficiency was 63.11%; after 24 h of self-repair at 80 °C, the tensile strength was 11.64 MPa, and the self-repair efficiency reached 94.79%. Then the sensors prepared by compounding with carbon nanotubes showed a good electrochemical response, and both slow and fast repeated bending of the finger wearing the sensors yielded significantly different electrical signal changes, and the sensors were cut off and still had the same function after self-repair at 30 °C, demonstrating their excellent potential for applications in soft robots, wearable devices, etc.

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (1) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (1) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

* References for papers published after 2023 are currently being built.