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Polymeric carbon nitrides produced from different gaseous conditions and their photocatalytic performance for degrading organic pollutants

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2023, 33(3), pp.803-809
  • DOI : 10.1007/s42823-023-00461-y
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : October 31, 2022
  • Accepted : January 7, 2023
  • Published : May 1, 2023

Jang Dawoon 1 Jeon Seokhyeon 1 Shin Eun Young 1 Park Sungjin 1

1Inha University

Accredited

ABSTRACT

Polymeric carbon nitride (p-C3N4) is a promising platform as a metal-free photo-catalyst for various reactions. The p-C3N4 can be produced by thermal poly-condensation of organic precursors. Their morphological and chemical structures depend on reaction conditions during the poly-condensation. In this study, two p-C3N4 materials are produced by heat treatment of urea under different gaseous conditions with air (urea-derived carbon nitride under air, UCN-A) and N2 (UCN-N), respectively. UCN-A and UCN-N samples are mesoporous materials and show excellent photocatalytic activities for degrading rhodamine B, an organic pollutant, under the irradiation of visible light. The UCN-A shows the better photocatalytic activity than UCN-N. Various characterizations reveal that more porous structures and larger surface areas of UCN-A are reasons for the better photocatalytic performance.

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