Recent advance of single atom-based photocatalysts for energy conversion and environmental purification

Niu Yaling; Yue Chengcai; Li Shuqi; Che Guangbo; Su Nan; Dong Hongjun; Li Chunmei

doi:10.1007/s42823-023-00486-3

Recent advance of single atom-based photocatalysts for energy conversion and environmental purification

Carbon Letters
Abbr : Carbon Lett.
2023, 33(4), pp.957-972
DOI : 10.1007/s42823-023-00486-3
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : October 29, 2022
Accepted : February 12, 2023
Published : June 1, 2023

Niu Yaling ¹, Yue Chengcai ¹, Li Shuqi ¹, Che Guangbo ¹, Su Nan ², Dong Hongjun ², Li Chunmei ²

¹Baicheng Normal University
²Jiangsu University

Accredited

ABSTRACT

Developing the high-performance semiconductor photocatalytic materials is an eternal topic under the background of the current energy and environment requirements. In recent years, single-atom photocatalysts (SAPCs) have been brought a lot of attention in energy conversion and environmental purification because of their unique characteristics and properties, including the unique coordination patterns, outstanding atomic utilization, quantum confinement effects, high catalytic activity, etc. Hence, this critical review focuses on the summarized various synthetic methods and the recent important applications of SAPCs, including photocatalytic H2 evolution (PHE) from water splitting, photocatalytic CO2 reduction, photodegradation of organic pollutants, etc. The prospects and challenges for future research topics of SAPCs with excellent activity and stability for various photocatalytic applications are prospected at the end of this review. We sincerely expect that this critical review can promote deep-level insight into the SAPCs subject for the future significant applications in other fields.

KEYWORDS

SAPCs Synthetic methods H2 evolution CO2 reduction Organic pollutant degradation

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (2) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (3) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

* References for papers published after 2023 are currently being built.

[journal] Chen R / 2022 / Spatiotemporal imaging of charge transfer in photocatalyst particles / Nature 610 : 296~301

[journal] Che H / 2021 / Iodideinduced fragmentation of polymerized hydrophilic carbon nitride for high-performance quasi-homogeneous photocatalytic H2O2production / Angew Chem Int Ed 60 : 25546~25550

[journal] Ruan X / 2022 / Favorable energy band alignment of TiO2anatase/rutile heterophase homojunctions yields photocatalytic hydrogen evolution with quantum efficiency exceeding 45. 6% / Adv Energy Mater 12 : 2200298~

[journal] Ma Yingdi / 2022 / Preparation of graphene–ZnO composite with enhanced photocatalytic performance / Carbon Letters / 한국탄소학회 32(5) : 1265~1275

[journal] Zhang Q / 2021 / Environmental phosphorylation"boosting photocatalytic CO2reduction over polymeric carbon nitride grown on carbon paper at air–liquid–solid joint interfaces / Chin J Catal 42 : 1667~1676

[journal] Li C / 2021 / High-efficient charge separation driven directionally by pyridine rings grafted on carbon nitride edge for boosting photocatalytic hydrogen evolution / Appl Catal B-Environ 297 : 120433~

[journal] Syed Noureen / 2022 / CQDs as emerging trends for future prospect in enhancement of photocatalytic activity / Carbon Letters / 한국탄소학회 32(1) : 81~97

[journal] Wan S / 2022 / Promoting intramolecular charge transfer of graphitic carbon nitride by donor–acceptor modulation for visible-light photocatalytic H2 evolution / Interdiscip Mater 1 : 294~308

[journal] Zhao G / 2022 / Two birds with one stone : engineering polymeric carbon nitride with n-π* electronic transition for extended light absorption and reduced charge recombination / Adv Powder Mater 2 : 100077~

[journal] Dong H / 2021 / Bimetallic synergetic regulating effect on electronic structure in cobalt/vanadium co-doped carbon nitride for boosting photocatalytic performance / Appl Catal B-Environ 287 : 119954~

[journal] Deng Hexia / 2022 / Oxygen vacancy engineering of TiO2-x nanostructures for photocatalytic CO2 reduction / Carbon Letters / 한국탄소학회 32(7) : 1671~1680

[journal] Li C / 2022 / Recent research progress of bimetallic phosphides-based nanomaterials as cocatalyst for photocatalytic hydrogen evolution / Chin Chem Lett 33 : 1141~1153

[journal] Jiang J / 2021 / Intercalation engineering of MXenes towards highly efficient photo(electrocatalytic)hydrogen evolution reactions / J Mater Chem A 9 : 24195~24214

[journal] Jin Tao / 2022 / Synthesis of g-C3N4/CQDs composite and its photocatalytic degradation property for Rhodamine B / Carbon Letters / 한국탄소학회 32(6) : 1451~1462

[journal] Ruan X / 2022 / Intramolecular heterostructured carbon nitride with heptazine-triazine for enhanced photocatalytic hydrogen evolution / Chem Eng J 428 : 132579~

[journal] Li M / 2022 / Construction double electric field of sulphur vacancies as medium ZnS/Bi2S3-PVDF self-supported recoverable piezoelectric film photocatalyst for enhanced photocatalytic performance / Appl Catal B-Environ 301 : 120792~

[journal] Qiao B / 2011 / Single-atom catalysis of CO oxidation using Pt1/FeOx / Nat Chem 3 : 634~641

[journal] Xue Z / 2022 / Single-atom catalysts for photocatalytic energy conversion / Joule 6 : 92~133

[journal] Gao C / 2020 / Heterogeneous single-atom photocatalysts : fundamentals and applications / Chem Rev 120 : 12175~12216

[journal] Wang J / 2021 / Porphyrin conjugated polymer with periodic typeII-like heterojunctions and single-atom catalytic sites for broadbandresponsive hydrogen evolution / Adv Funct Mater 31 : 2009819~

[journal] Shangguan Y / 2021 / Bandgap engineering of tetragonal phase CuFeS2quantum dots via mixed-valence singleatomic Ag decoration for synergistic Cr(VI)reduction and RhB degradation / Chin Chem Lett 32 : 3450~3456

[journal] Gao W / 2021 / Vacancy-defect modulated pathway of photoreduction of CO2on single atomically thin AgInP2S6sheets into olefiant gas / Nat Commun 12 : 4747~

[journal] Xu Q / 2021 / Single-atom site catalysts supported on two-dimensional materials for energy applications / Chin Chem Lett 32 : 3771~3781

[journal] Swain S / 2022 / A comprehensive study on heterogeneous single atom catalysis : current progress, and challenges / Coordin Chem Rev 470 : 214710~

[journal] Gao M / 2022 / Fast charge separation and transfer strategy in polymeric carbon nitride for efficient photocatalytic H2evolution : coupling surface schottky junctions and interlayer charge transfer channels / Nano Energy 103 : 107767~

[journal] Jiang W / 2021 / Photocatalyst for high-performance H2production : Ga-doped polymeric carbon nitride / Angew Chem Int Ed 60 : 6124~6129

[journal] Shangguan Y / 2022 / Interfacial engineering of CuFeS2quantum dots via platinum decoration with enhanced Cr(VI)reduction dynamics under UV–vis-NIR radiation / J Hazard Mater 421 : 126701~

[journal] Zhang F / 2021 / Single tungsten atom steered band-gap engineering for graphitic carbon nitride ultrathin nanosheets boosts visible-light photocatalytic H2evolution / Chem Eng J 424 : 130004~

[journal] Han C / 2023 / Enhanced support effects in single-atom copper-incorporated carbon nitride for photocatalytic suzuki cross-coupling reactions / Appl Catal B-Environ 320 : 121954~

[journal] Huang Y / 2022 / Pt Atoms/clusters on Ni-phytate-sensitized carbon nitride for enhanced NIR-light-driven overall water splitting beyond 800nm / Angew Chem Int Ed 61 : e202212234~

[journal] Liu M / 2022 / A facile complexing agent-assistant single atom Ag-N3S1 site photodeposition strategy / Appl Catal B-Environ 318 : 121896~

[journal] Selvakumar K / 2022 / Single metal atom oxide anchored Fe3O4-ED-rGO for highly efficient photodecomposition of antibiotic residues under visible light illumination / Appl Catal B-Environ 300 : 120740~

[journal] Lee B / 2019 / Reversible and cooperative photoactivation of single-atom Cu/TiO2 photocatalysts / Nat Mater 18 : 620~626

[journal] Zhao Q / 2017 / Effective and durable Co single atomic cocatalysts for photocatalytic hydrogen production / ACS Appl Mater Interfaces 9 : 42734~42741

[journal] Xiang Y / 2020 / Constructing electron delocalization channels in covalent organic frameworks powering CO2photoreduction in water / Appl Catal B-Envirn 274 : 119096~

[journal] Ma X / 2021 / Modulating coordination environment of single-atom catalysts and their proximity to photosensitive units for boosting MOF photocatalysis / J Am Chem Soc 143 : 12220~12229

[journal] Sharma P / 2021 / Carbon nitride-based ruthenium single atom photocatalyst for CO2reduction to methanol / Small 17 : 2006478~

[journal] Luo H / 2020 / Pt single-atoms supported on nitrogen-doped carbon dots for highly efficient photocatalytic hydrogen generation / J Mater Chem A 8 : 14690~14696

[journal] Qiu S / 2019 / Carbon dots decorated ultrathin CdS nanosheets enabling in-situ anchored Pt single atoms : a highly efficient solardriven photocatalyst for hydrogen evolution / Appl Catal B-Environ 259 : 118036~

[journal] Li C / 2022 / Synergies of adjacent sites in atomically dispersed ruthenium toward achieving stable hydrogen evolution / Inorg Chem 61 : 13453~13461

[journal] Xu T / 2020 / Atomically Pt implanted nanoporous TiO2film for photocatalytic degradation of trace organic pollutants in water / Chem Eng J 385 : 123832~

[journal] Xiong X / 2020 / Photocatalytic CO2reduction to CO over Ni single atoms supported on defect-rich zirconia / Adv Energy Mater 10 : 2002928~

[journal] Wang T / 2021 / Synergistic Pd single atoms, clusters, and oxygen vacancies on TiO2for photocatalytic hydrogen evolution coupled with selective organic oxidation / Small 17 : 2006255~

[journal] Fang X / 2018 / Single Pt atoms confined into a metal-organic framework for efficient photocatalysis / Adv Mater 30 : 1705112~

[journal] Chen Y / 2020 / Engineering the atomic interface with single platinum atoms for enhanced photocatalytic hydrogen production / Angew Chem Int Ed 59 : 1295~1301

[journal] Zhou P / 2019 / Strengthening reactive metal-support interaction to stabilize high-density Pt single atoms on electron-deficient g-C3N4 for boosting photocatalytic H2production / Nano Energy 56 : 127~137

[journal] Yu Y / 2021 / Synergistic effect of Cu single atoms and Au–Cu alloy nanoparticles on TiO2for efficient CO2photoreduction / ACS Nano 15 : 14453~14464

[journal] Zhou P / 2020 / Metal single atom strategy greatly boosts photocatalytic methyl activation and C–C coupling for the coproduction of high-value added multicarbon compounds and hydrogen / ACS Catal 10 : 9109~9114

[journal] Sharma P / 2021 / Carbon nitride-based ruthenium single atom photocatalyst for CO2reduction to methanol / Small 17 : 2006478~

[journal] Yan T / 2020 / Bismuth atom tailoring of indium oxide surface frustrated Lewis pairs boosts heterogeneous CO2photocatalytic hydrogenation / Nat Commun 11 : 6095~

[journal] Ni L / 2022 / Significantly enhanced photocatalytic performance of the g-C3N4/sulfur-vacancy-containing Zn3In2S6heterostructure for photocatalytic H2and H2O2generation by coupling defects with heterojunction engineering / Inorg Chem 61 : 19552~19566

[journal] Li M / 2021 / Construction photothermal/pyroelectric property of hollow FeS2/Bi2S3 nanostructure with enhanced full spectrum photocatalytic activity / Appl Catal B-Environ 298 : 120573~

[journal] Zhou T / 2022 / Synergistic effect triggered by skeleton delocalization and edge induction of carbon nitride expedites photocatalytic hydrogen evolution / Chem Eng J 442 : 136190~

[journal] Ruan X / 2022 / A twin S-Scheme artificial photosynthetic system with self-assembled heterojunctions yields superior photocatalytic hydrogen evolution rate / Adv Mater 35 : 2209141~

[journal] Zhou T / 2023 / Advancing n-p* electron transition of carbon nitride via distorted structure and nitrogen heterocycle for efficient photodegradation : performance, mechanism and toxicity insight / J Colloid Interf Sci 632 : 285~298

[journal] Alarawi A / 2019 / Recent advances in emerging single atom confined two-dimensional materials for water splitting applications / Mater Today Energy 11 : 1~23

[journal] Zhang J / 2019 / Uniform permutation of quasi-2D perovskites by vacuum poling for efficient, high-fill-factor solar cells / Joule 12 : 3061~3071

[journal] Zhou P / 2021 / Single-atom Pt-I3 sites on allinorganic Cs2SnI6perovskite for efficient photocatalytic hydrogen production / Nat Commun 12 : 4412~

[journal] Li Y / 2022 / In situ photodeposition of platinum clusters on a covalent organic framework for photocatalytic hydrogen production / Nat Commun 13 : 1355~

[journal] Wang C / 2021 / Co and Pt dual-single-atoms with oxygen-coordinated Co–O–Pt dimer sites for ultrahigh photocatalytic hydrogen evolution efficiency / Adv Mater 33 : 2003327~

[journal] Hiragond C / 2022 / Single-atom catalysts(SACs)for photocatalytic CO2reduction with H2O : activity, product selectivity, stability, and surface chemistry / Small 18 : 2201428~

[journal] Si S / 2022 / Lowcoordination single Au atoms on ultrathin ZnIn2S4nanosheets for selective photocatalytic CO2reduction towards CH4 / Angew Chem Int Ed 61 : e202209446~

[journal] Ji S / 2020 / Rare-earth single erbium atoms for enhanced photocatalytic CO2reduction / Angew Chem Int Ed 59 : 10651~10657

[journal] Xiao Y / 2023 / Construction of core-shell CeO2nanorods/SnIn4S8 nanosheets heterojunction with rapid spatial electronic migration for effective wastewater purification and H2O2production / Sep Purif Technol 304 : 122385~

[journal] Li S / 2022 / S-scheme photocatalyst TaON/Bi2WO6 nanofibers with oxygen vacancies for efficient abatement of antibiotics and Cr(VI) : intermediate eco-toxicity analysis and mechanistic insights / Chin J Catal 43 : 2652~2664

[journal] Li S / 2023 / Constructing Cd0. 5Zn0. 5S/Bi2WO6 S-scheme heterojunction for boosted photocatalytic antibiotic oxidation and Cr(VI)reduction / Adv Powder Mater 2 : 100073~

[journal] Shi J / 2023 / Intramolecular D-A structure and n-π* transition co-promoted photodegradation activity of carbon nitride : Performance, mechanism and toxicity insight / Chem Eng J 456 : 141029~

[journal] Wang L / 2023 / One-step purification of target enzymes using interaction-and structure-based design of aptamer-affinity responsive polymers : Selective immobilization and enhanced stability / Sep Purif Technol 307 : 122758~

[journal] Cai T / 2022 / Single-atom site catalysts for environmental remediation : recent advances / J Hazard, Mater 440 : 129772~

[journal] Zhang C / 2022 / Dual optimization approach to Mo single atom dispersed g-C3N4 photocatalyst : morphology and defect evolution / Appl Catal B-Environ 303 : 120904~

[journal] Rong P / 2022 / Photocatalytic degradation of methylene blue(MB)with Cu1–ZnO single atom catalysts on graphenecoated flexible substrates / J Mater Chem A 10 : 6231~

[journal] Huang S / 2022 / Multiple catalytic sites of Fe-Nx and Fe–N–C single atoms embedded N-doped carbon heterostructures for high-efficiency removal of malachite green / Chem Eng J 430 : 132933~

[journal] Wang R / 2022 / Noble-metal-free Co-N-graphene/PDI for significant enhancement of photocatalytic performance / J Alloy Compd 925 : 166370~

[journal] Qin Z / 2022 / Tailoring optical and photocatalytic properties by single-Ag-atom exchange in Au13Ag12(PPh3)10Cl8 nanoclusters / Nano Res 15 : 2971~2976

[journal] Lv X / 2019 / Metal-free B@g-CN : visible/infrared light-driven single atom photocatalyst enables spontaneous dinitrogen reduction to ammonia / Nano Lett 19 : 6391~6399

[journal] Peng H / 2022 / Ru/In dual-single atoms modulated charge separation for significantly accelerated photocatalytic H2evolution in pure water / Adv Energy Mater 12 : 2201688~

[journal] Shi X / 2022 / Highly selective photocatalytic CO2methanation with water vapor on single-atom platinum-decorated defective carbon nitride / Angew Chem Int Ed 61 : e202203063~

[journal] Gao C / 2018 / Heterogeneous single-atom catalyst for visible-light-driven high-turnover CO2reduction / Adv Mater 30 : 1704624~

[journal] Zhang H / 2016 / Efficient visible-lightdriven carbon dioxide reduction by a single-atom implanted metal–organic framework / Angew Chem Int Ed 55 : 14310~14314

[journal] Yang Y / 2020 / In situ grown singleatom cobalt on polymeric carbon nitride with bidentate ligand for efficient photocatalytic degradation of refractory antibiotics / Small 29 : 2001634~

[journal] Wang X / 2022 / Au single atom-anchored WO3/TiO2 nanotubes for the photocatalytic degradation of volatile organic compounds / J Mater Chem A 10 : 6078~6085

[journal] Zhou Z / 2021 / Boosting the activation of molecular oxygen and the degradation of tetracycline over high loading Ag single atomic catalyst / Water Res 201 : 117314~

[journal] Zhao G / 2022 / Single atom Fedispersed graphitic carbon nitride(g-C3N4)as a highly efficient peroxymonosulfate photocatalytic activator for sulfamethoxazole degradation / Chem Eng J 430 : 132937~

[journal] Wei W / 2022 / Loading Rh single atoms onto hollow cubic Cu2MoS4nanoparticles for decreased electron/hole recombination and increased photocatalytic performance / J Alloy Compd 896 : 162832~

[journal] Chen J / 2022 / Rare-earth single atoms decorated 2D-TiO2 nanosheets for the photodegradation of gaseous O-xylene / J Colloid Interf Sci 605 : 674~684

KJCKorea
Journal Central

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Recent advance of single atom-based photocatalysts for energy conversion and environmental purification

ABSTRACT

KEYWORDS

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (2) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (3) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 6.04

Recent advance of single atom-based photocatalysts for energy conversion and environmental purification

ABSTRACT

KEYWORDS

Statistics

Tools

Issue List

Citation status

KCI Citation Counts (0)

WoS Citation Counts (2) This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (2) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (3) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

REFERENCES (85) * References for papers published after 2023 are currently being built.

Search PDF

Citation

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

* References for papers published after 2023 are currently being built.