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Co-intercalation into graphite of lithium, potassium and barium using LiCl–KCl molten salt

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2023, 33(5), pp.1303-1309
  • DOI : 10.1007/s42823-022-00352-8
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : March 10, 2022
  • Accepted : May 2, 2022
  • Published : August 1, 2023

Hajj Inass El 1 Speyer Lucie 1 Cahen Sébastien 1 Berger Pascal 2 Medjahdi Ghouti 1 Lagrange Philippe 1 Claire Hérold 1

1Université de Lorraine, CNRS, IJL, 54000, Nancy, France
2NIMBE, CEA, CNRS, Université Paris-Saclay, CEA Saclay, 91191, Gif sur Yvette Cedex, France

Accredited

ABSTRACT

The synthesis of a novel first stage GIC containing simultaneously lithium, potassium and barium through a solid–liquid reaction by molten salts method is described. Such a route has been largely developed in our laboratory for intercalation of metals into graphite. The interplanar distance of this quaternary compound reaches 950 pm and exhibits poly-layered intercalated sheets defined by X-ray measurements. The Li0.2K0.75Ba0.6C6 chemical formula of the compound is determined by ion beam analysis and this GIC is remarkably homogeneous. This GIC is the first poly-layered one containing barium.

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