Mechanism of activated carbon-catalyzed methane decomposition process for the production of hydrogen and high-value carbon

Yun Ji Su; Kim Ji Hong; Kang Seok Chang; Im Ji Sun

doi:10.1007/s42823-023-00516-0

Mechanism of activated carbon-catalyzed methane decomposition process for the production of hydrogen and high-value carbon

Carbon Letters
Abbr : Carbon Lett.
2023, 33(6), pp.1799-1809
DOI : 10.1007/s42823-023-00516-0
Publisher : Korean Carbon Society
Research Area : Natural Science > Natural Science General > Other Natural Sciences General
Received : March 23, 2023
Accepted : April 6, 2023
Published : October 1, 2023

Yun Ji Su ¹, Kim Ji Hong ¹, Kang Seok Chang ¹, Im Ji Sun ¹

¹C1 Gas & Carbon Convergent Research Center, Korea Research Institute of Chemical Technology (KRICT)

Accredited

ABSTRACT

The thermocatalytic decomposition of methane is a promising method for hydrogen production. To determine the cause of carbonaceous catalyst deactivation and to produce high-value carbon, methane decomposition behavior and deactivated catalysts were analyzed. The surface properties and crystallinity of a commercial activated carbon material, MSP20, used as a methane decomposition catalyst, varied with the reaction time at a reaction temperature of 900 °C. During the initial reaction, MSP20 provided a methane conversion of ≥ 50%; however, the catalyst exhibited rapid deactivation as crystalline carbon grew at surface defects; after 15 min of reaction, approximately 33% methane conversion was maintained. With increasing reaction time, the specific surface area of the catalyst decreased, whereas crystallinity increased. The R-square value of the conversion–crystallinity relationship was significantly higher than that of the conversion–specific surface area relationship; however, neither profile was linear. The activity of the activated carbon catalyst for methane decomposition is mainly determined by the complex actions of the specific surface area and defect sites. The activity was maintained after an initial sharp decline caused by the continuous growth of crystalline carbon product. This study presents the application of carbonaceous catalysts for the decomposition reaction of methane to form COx-free hydrogen, while simultaneously yielding porous carbon materials with an improved electrical conductivity.

KEYWORDS

Activated carbon Methane decomposition Hydrogen Mechanism High-value carbon

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Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 4.82

Mechanism of activated carbon-catalyzed methane decomposition process for the production of hydrogen and high-value carbon

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Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (3) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (1) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

* References for papers published after 2023 are currently being built.

Carbon Letters 2023 KCI Impact Factor : 1.35 KCI-WoS Impact Factor : 4.82

Mechanism of activated carbon-catalyzed methane decomposition process for the production of hydrogen and high-value carbon

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WoS Citation Counts (3) This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (3) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (1) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-07-01)

REFERENCES (56) * References for papers published after 2023 are currently being built.

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This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

* References for papers published after 2023 are currently being built.