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A high sensitivity strategy of nitrite detection based on CoFe@NC nanocubes modified glassy carbon electrode

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2023, 33(7), pp.2075-2086
  • DOI : 10.1007/s42823-023-00558-4
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : May 17, 2023
  • Accepted : June 11, 2023
  • Published : December 1, 2023

Zou Yanjiao 1 Gu Hongfei 1 Yang Jingjing 1 Zeng Ting 1 Yang Juan 1 Zhang Yuanyuan 1

1Wuhan Institute of Technology

Accredited

ABSTRACT

In the present study, an innovative electrochemical sensing platform was established for sensitive detection of NO2—. This sensor was developed using CoFe alloy encapsulated in nitrogen-doped carbon nanocubes (named as CoFe@NC-NCS), synthesized through the calcination of polydopamine-coated CoFe Prussian-blue analogues (CoFe-PBA@PDA). The morphological and electrochemical characterization reveals that the CoFe@NC-NCS possesses high electrocatalytic activity for electrochemical quantitation of NO2—, ascribed to the huge surface area and plentiful active positions, benefiting from the porous, hollow, and core–shell structure of CoFe@NC-NCS. Under the optimal conditions, CoFe@NC-NCS/GCE possessed remarkable sensing performance for NO2— with wide liner ranges and a detection limit of 0.015 μM. NO2— recovery experiments in real samples exhibited recoveries in the range of 98.8–103.5%. Hence, the CoFe@NC-NCS shows great promise for the construction of electrochemical sensor with more potential application.

Citation status

This is the result of checking the information with the same ISSN, publication year, volume, and start page between the WoS and the KCI journals. (as of 2024-07-26)

Total Citation Counts(KCI+WOS) (18) This is the number of times that the duplicate count has been removed by comparing the citation list of WoS and KCI.

Scopus Citation Counts (31) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2025-01-01)

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