@article{ART003059364},
author={Myeong Seongjae and Ha Seongmin and Lim Chaehun and Min Chung Gi and Lee, Young-Seak},
title={Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors},
journal={Carbon Letters},
issn={1976-4251},
year={2024},
volume={34},
number={1},
pages={65-74},
doi={10.1007/s42823-023-00668-z}
TY - JOUR
AU - Myeong Seongjae
AU - Ha Seongmin
AU - Lim Chaehun
AU - Min Chung Gi
AU - Lee, Young-Seak
TI - Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors
JO - Carbon Letters
PY - 2024
VL - 34
IS - 1
PB - Korean Carbon Society
SP - 65
EP - 74
SN - 1976-4251
AB - Fluorine heteroatoms were introduced to increase the limited specific capacitances of electric double-layer capacitors (EDLCs), and the effects of the fluorine atoms were analyzed. To introduce the fluorine, a CF4 plasma treatment was used that introduced the fluorine atoms quickly. Among the fluorine functional groups in the F6-ACA framework, the semi-ionic C–F bonds induced rapid charge transfer and imparted pseudocapacitance. Consequently, we achieved a specific capacitance of 325.68 F/g for the F6-CA sample at 0.5 A/g. By analyzing the contributions of the electric double-layer capacitance and the pseudocapacitance, we determined that the contribution from the pseudocapacitance was 37.57%. A remarkable specific capacitance retention rate of 95.87% was obtained over 1000 charge/discharge cycles with a high current density of 3 A/g. Additionally, the semi-ionic C–F bonds reduced the charge transfer resistance (Rct) by 36.8%. Therefore, the specific capacitance was improved by the fluorine heteroatoms, and the semi-ionic C–F bonds played a pivotal role in this improvement.
KW - CF4 plasma Carbon aerogel Supercapacitor Semi-ionic C–F bond Trasatti’s method Dunn’s method
DO - 10.1007/s42823-023-00668-z
ER -
Myeong Seongjae, Ha Seongmin, Lim Chaehun, Min Chung Gi and Lee, Young-Seak. (2024). Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors. Carbon Letters, 34(1), 65-74.
Myeong Seongjae, Ha Seongmin, Lim Chaehun, Min Chung Gi and Lee, Young-Seak. 2024, "Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors", Carbon Letters, vol.34, no.1 pp.65-74. Available from: doi:10.1007/s42823-023-00668-z
Myeong Seongjae, Ha Seongmin, Lim Chaehun, Min Chung Gi, Lee, Young-Seak "Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors" Carbon Letters 34.1 pp.65-74 (2024) : 65.
Myeong Seongjae, Ha Seongmin, Lim Chaehun, Min Chung Gi, Lee, Young-Seak. Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors. 2024; 34(1), 65-74. Available from: doi:10.1007/s42823-023-00668-z
Myeong Seongjae, Ha Seongmin, Lim Chaehun, Min Chung Gi and Lee, Young-Seak. "Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors" Carbon Letters 34, no.1 (2024) : 65-74.doi: 10.1007/s42823-023-00668-z
Myeong Seongjae; Ha Seongmin; Lim Chaehun; Min Chung Gi; Lee, Young-Seak. Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors. Carbon Letters, 34(1), 65-74. doi: 10.1007/s42823-023-00668-z
Myeong Seongjae; Ha Seongmin; Lim Chaehun; Min Chung Gi; Lee, Young-Seak. Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors. Carbon Letters. 2024; 34(1) 65-74. doi: 10.1007/s42823-023-00668-z
Myeong Seongjae, Ha Seongmin, Lim Chaehun, Min Chung Gi, Lee, Young-Seak. Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors. 2024; 34(1), 65-74. Available from: doi:10.1007/s42823-023-00668-z
Myeong Seongjae, Ha Seongmin, Lim Chaehun, Min Chung Gi and Lee, Young-Seak. "Effect of fluorine functional groups introduced into activated carbon aerogel by carbon tetrafluoride plasmas in supercapacitors" Carbon Letters 34, no.1 (2024) : 65-74.doi: 10.1007/s42823-023-00668-z
