@article{ART003062913},
author={Vu Xuan Minh and Le Thi My Hanh and Bui Van Cuong and Nguyen Tuan Dung and Hrynshpan D. D. and Le Van Thuan and Tran Dai Lam and Nguyen Thi Phuong Lan and Pham Thi Lan},
title={A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions},
journal={Carbon Letters},
issn={1976-4251},
year={2024},
volume={34},
number={2},
pages={769-782},
doi={10.1007/s42823-023-00598-w}
TY - JOUR
AU - Vu Xuan Minh
AU - Le Thi My Hanh
AU - Bui Van Cuong
AU - Nguyen Tuan Dung
AU - Hrynshpan D. D.
AU - Le Van Thuan
AU - Tran Dai Lam
AU - Nguyen Thi Phuong Lan
AU - Pham Thi Lan
TI - A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions
JO - Carbon Letters
PY - 2024
VL - 34
IS - 2
PB - Korean Carbon Society
SP - 769
EP - 782
SN - 1976-4251
AB - Activated carbon (AC) is a versatile and extensively employed adsorbent in environmental remediation. It possesses distinct properties that can be enhanced to selectively target specific pollutants through modifications, including chemical impregnation or incorporation into composite materials. In this study, porous calcium alginate beads (PCAB) were synthesized by incorporating AC and natural alginate through ion gelation in a Ca(II) ion-containing solution, with the addition of sodium lauryl sulfate as a surfactant. The prepared PCAB was tested for Cu(II) removal. PCAB exhibited a spherical shape with higher porosity and surface area (160.19 m2.g−1) compared to calcium alginate beads (CAB) (0.04 m2.g−1). The adsorption kinetics followed the pseudo-first-order model for PCAB and the pseudo-second-order model for CAB. The Langmuir isotherm model provided the best fit for adsorption on PCAB, while the Freundlich model was suitable for CAB. Notably, PCAB demonstrated a maximum adsorption capacity of 75.54 mg.g−1, significantly higher than CAB's capacity of 9.16 mg.g−1. Desorption studies demonstrated that 0.1 M CaCl2 exhibited the highest efficiency (90%) in desorbing Cu(II) ions from PCAB, followed by 0.1 M HCl and 0.1 M NaCl. PCAB showed efficient reusability for up to four consecutive adsorption–desorption cycles. The fixed-bed column experiment confirmed the match with the Thomas model to the breakthrough curves with qTH of 120.12 mg.g−1 and 68.03 mg.g−1 at a flow rate of 1 mL.min−1 and 2 mL.min−1, respectively. This study indicated that PCAB could be an effective adsorbent for Cu(II) removal, offering insights for further application and design considerations.
KW - Activated carbon Natural alginate Porous adsorbent beads Adsorption Cu(II) ion removal
DO - 10.1007/s42823-023-00598-w
ER -
Vu Xuan Minh, Le Thi My Hanh, Bui Van Cuong, Nguyen Tuan Dung, Hrynshpan D. D., Le Van Thuan, Tran Dai Lam, Nguyen Thi Phuong Lan and Pham Thi Lan. (2024). A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions. Carbon Letters, 34(2), 769-782.
Vu Xuan Minh, Le Thi My Hanh, Bui Van Cuong, Nguyen Tuan Dung, Hrynshpan D. D., Le Van Thuan, Tran Dai Lam, Nguyen Thi Phuong Lan and Pham Thi Lan. 2024, "A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions", Carbon Letters, vol.34, no.2 pp.769-782. Available from: doi:10.1007/s42823-023-00598-w
Vu Xuan Minh, Le Thi My Hanh, Bui Van Cuong, Nguyen Tuan Dung, Hrynshpan D. D., Le Van Thuan, Tran Dai Lam, Nguyen Thi Phuong Lan, Pham Thi Lan "A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions" Carbon Letters 34.2 pp.769-782 (2024) : 769.
Vu Xuan Minh, Le Thi My Hanh, Bui Van Cuong, Nguyen Tuan Dung, Hrynshpan D. D., Le Van Thuan, Tran Dai Lam, Nguyen Thi Phuong Lan, Pham Thi Lan. A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions. 2024; 34(2), 769-782. Available from: doi:10.1007/s42823-023-00598-w
Vu Xuan Minh, Le Thi My Hanh, Bui Van Cuong, Nguyen Tuan Dung, Hrynshpan D. D., Le Van Thuan, Tran Dai Lam, Nguyen Thi Phuong Lan and Pham Thi Lan. "A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions" Carbon Letters 34, no.2 (2024) : 769-782.doi: 10.1007/s42823-023-00598-w
Vu Xuan Minh; Le Thi My Hanh; Bui Van Cuong; Nguyen Tuan Dung; Hrynshpan D. D.; Le Van Thuan; Tran Dai Lam; Nguyen Thi Phuong Lan; Pham Thi Lan. A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions. Carbon Letters, 34(2), 769-782. doi: 10.1007/s42823-023-00598-w
Vu Xuan Minh; Le Thi My Hanh; Bui Van Cuong; Nguyen Tuan Dung; Hrynshpan D. D.; Le Van Thuan; Tran Dai Lam; Nguyen Thi Phuong Lan; Pham Thi Lan. A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions. Carbon Letters. 2024; 34(2) 769-782. doi: 10.1007/s42823-023-00598-w
Vu Xuan Minh, Le Thi My Hanh, Bui Van Cuong, Nguyen Tuan Dung, Hrynshpan D. D., Le Van Thuan, Tran Dai Lam, Nguyen Thi Phuong Lan, Pham Thi Lan. A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions. 2024; 34(2), 769-782. Available from: doi:10.1007/s42823-023-00598-w
Vu Xuan Minh, Le Thi My Hanh, Bui Van Cuong, Nguyen Tuan Dung, Hrynshpan D. D., Le Van Thuan, Tran Dai Lam, Nguyen Thi Phuong Lan and Pham Thi Lan. "A promising composite adsorbent of activated carbon and natural alginate for Cu(II) ion removal from aqueous solutions" Carbon Letters 34, no.2 (2024) : 769-782.doi: 10.1007/s42823-023-00598-w
