@article{ART003087303},
author={Wan Yang and Liu Qi and Xu Zenghui and Li Jinze and Wang Huijie and Xu Mengyang and Yan Chenlong and Song Xianghai and Liu Xin and Wang Huiqin and Zhou Weiqiang and Huo Pengwei},
title={Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction},
journal={Carbon Letters},
issn={1976-4251},
year={2024},
volume={34},
number={4},
pages={1143-1154},
doi={10.1007/s42823-023-00683-0}
TY - JOUR
AU - Wan Yang
AU - Liu Qi
AU - Xu Zenghui
AU - Li Jinze
AU - Wang Huijie
AU - Xu Mengyang
AU - Yan Chenlong
AU - Song Xianghai
AU - Liu Xin
AU - Wang Huiqin
AU - Zhou Weiqiang
AU - Huo Pengwei
TI - Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction
JO - Carbon Letters
PY - 2024
VL - 34
IS - 4
PB - Korean Carbon Society
SP - 1143
EP - 1154
SN - 1976-4251
AB - CO2 photocatalytic reduction is a carbon–neutral renewable energy technology. However, this technology is restricted by the low utilization of photocatalytic electrons. Therefore, to improve the separation efficiency of photogenerated carriers and enhance the performance of CO2 photocatalytic reduction. In this paper, g-C3N4/Pd composite with Schottky junction was synthesized by using g-C3N4, a two-dimensional material with unique interfacial effect, as the substrate material in combination with the co-catalyst Pd. The composite of Pd and g-C3N4 was tested to have a strong localized surface plasmon resonance effect (LSPR), which decreased the reaction barriers and improved the electron utilization. The combination of reduced graphene oxide (rGO) created a π–π conjugation effect at the g-C3N4 interface, which shortened the electron migration path and further improved the thermal electron transfer and utilization efficiency. The results show that the g-C3N4/rGO/Pd (CRP) exhibits the best performance for photocatalytic reduction of CO2, with the yields of 13.57 μmol g−1 and 2.73 μmol g−1 for CO and CH4, respectively. Using the in situ infrared test to elucidate the intermediates and the mechanism of g-C3N4/rGO/Pd (CRP) photocatalytic CO2 reduction. This paper provides a new insight into the interface design of photocatalytic materials and the application of co-catalysts.
KW - Co-catalysts Photocatalysis CO2 reduction Localized surface plasmon resonance effect Synergistic effect Ultrathin Pd nanosheets
DO - 10.1007/s42823-023-00683-0
ER -
Wan Yang, Liu Qi, Xu Zenghui, Li Jinze, Wang Huijie, Xu Mengyang, Yan Chenlong, Song Xianghai, Liu Xin, Wang Huiqin, Zhou Weiqiang and Huo Pengwei. (2024). Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction. Carbon Letters, 34(4), 1143-1154.
Wan Yang, Liu Qi, Xu Zenghui, Li Jinze, Wang Huijie, Xu Mengyang, Yan Chenlong, Song Xianghai, Liu Xin, Wang Huiqin, Zhou Weiqiang and Huo Pengwei. 2024, "Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction", Carbon Letters, vol.34, no.4 pp.1143-1154. Available from: doi:10.1007/s42823-023-00683-0
Wan Yang, Liu Qi, Xu Zenghui, Li Jinze, Wang Huijie, Xu Mengyang, Yan Chenlong, Song Xianghai, Liu Xin, Wang Huiqin, Zhou Weiqiang, Huo Pengwei "Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction" Carbon Letters 34.4 pp.1143-1154 (2024) : 1143.
Wan Yang, Liu Qi, Xu Zenghui, Li Jinze, Wang Huijie, Xu Mengyang, Yan Chenlong, Song Xianghai, Liu Xin, Wang Huiqin, Zhou Weiqiang, Huo Pengwei. Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction. 2024; 34(4), 1143-1154. Available from: doi:10.1007/s42823-023-00683-0
Wan Yang, Liu Qi, Xu Zenghui, Li Jinze, Wang Huijie, Xu Mengyang, Yan Chenlong, Song Xianghai, Liu Xin, Wang Huiqin, Zhou Weiqiang and Huo Pengwei. "Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction" Carbon Letters 34, no.4 (2024) : 1143-1154.doi: 10.1007/s42823-023-00683-0
Wan Yang; Liu Qi; Xu Zenghui; Li Jinze; Wang Huijie; Xu Mengyang; Yan Chenlong; Song Xianghai; Liu Xin; Wang Huiqin; Zhou Weiqiang; Huo Pengwei. Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction. Carbon Letters, 34(4), 1143-1154. doi: 10.1007/s42823-023-00683-0
Wan Yang; Liu Qi; Xu Zenghui; Li Jinze; Wang Huijie; Xu Mengyang; Yan Chenlong; Song Xianghai; Liu Xin; Wang Huiqin; Zhou Weiqiang; Huo Pengwei. Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction. Carbon Letters. 2024; 34(4) 1143-1154. doi: 10.1007/s42823-023-00683-0
Wan Yang, Liu Qi, Xu Zenghui, Li Jinze, Wang Huijie, Xu Mengyang, Yan Chenlong, Song Xianghai, Liu Xin, Wang Huiqin, Zhou Weiqiang, Huo Pengwei. Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction. 2024; 34(4), 1143-1154. Available from: doi:10.1007/s42823-023-00683-0
Wan Yang, Liu Qi, Xu Zenghui, Li Jinze, Wang Huijie, Xu Mengyang, Yan Chenlong, Song Xianghai, Liu Xin, Wang Huiqin, Zhou Weiqiang and Huo Pengwei. "Interface engineering enhanced g-C3N4/rGO/Pd composites synergetic localized surface plasmon resonance effect for boosting photocatalytic CO2 reduction" Carbon Letters 34, no.4 (2024) : 1143-1154.doi: 10.1007/s42823-023-00683-0
