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Improvement of the electrochemical properties of Li/CFx primary batteries induced by Nitrogen plasma treatment from silica and carbon fluoride

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2024, 34(5), pp.1521-1528
  • DOI : 10.1007/s42823-024-00719-z
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : January 12, 2024
  • Accepted : March 9, 2024
  • Published : June 14, 2024

Ha Seongmin 1 Lim Chaehun 2 Myeong Seongjae 3 Lee In Woo 2 Lee, Young-Seak 2

1충남대학교 응용화학공학과
2충남대학교
3Chungnam National University

Accredited

ABSTRACT

The electrochemical properties of a CFX cathode were improved by defluorination of the surface with a N2 plasma and using a silica wafer. Compared to the N2 plasma treatment alone, when the CFX and silica were reacted together, the C-F bonds were modified and the surface was etched efficiently, so defluorination was enhanced. An electrochemical analysis confirmed that Half-cells prepared by treating CFx and silica with nitrogen plasma exhibited a capacity of about 400 mAh/g at 5C. In addition, it was confirmed that the loss of charge transfer was reduced by up to 71% compared to that for pristine CFX. As shown by a GITT analysis, when the CFx and silica were treated with N2 plasma together, the ion conductivity gradually increased due to a decrease in the ion diffusion barriers and the formation of a carbon layer. Therefore, this is a simple and effective way to improve the conductivities of CFX cathode materials with the energy of a N2 plasma and the silica-fluorine reaction.

Citation status

Scopus Citation Counts (3) This is the result of checking the information with the same ISSN, publication year, volume, and start page between articles in KCI and the SCOPUS journals. (as of 2024-10-01)

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