@article{ART003119261},
author={Park Jae Seo and Jeong Yeon Jeong and Park Dong Yoon and Shin Hyun Ji and Jang Da Hee and Kim So Eun and RYU JEONG HEON and Yang Seo Mi and Kim Jang-Yul and KIM,JAE-HO and Yang Seung Jae},
title={Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode},
journal={Carbon Letters},
issn={1976-4251},
year={2024},
volume={34},
number={7},
pages={1971-1980},
doi={10.1007/s42823-024-00740-2}
TY - JOUR
AU - Park Jae Seo
AU - Jeong Yeon Jeong
AU - Park Dong Yoon
AU - Shin Hyun Ji
AU - Jang Da Hee
AU - Kim So Eun
AU - RYU JEONG HEON
AU - Yang Seo Mi
AU - Kim Jang-Yul
AU - KIM,JAE-HO
AU - Yang Seung Jae
TI - Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode
JO - Carbon Letters
PY - 2024
VL - 34
IS - 7
PB - Korean Carbon Society
SP - 1971
EP - 1980
SN - 1976-4251
AB - Mesocrystals are macroscopic structures formed by the assembly of nanoparticles that possess distinct surface structures and collective properties when compared to traditional crystalline materials. Various growth mechanisms and their unique features have promise as material design tools for diverse potential applications. This paper presents a straightforward method for metal–organic coordination-based mesocrystals using nickel ions and terephthalic acid. The coordinative compound between Ni2+ and terephthalic acid drives the particle-mediated growth mechanism, resulting in the mesocrystal formation through a mesoscale assembly. Subsequent carbonization converts mesocrystals to multidirectional interconnected graphite nanospheres along the macroscopic framework while preserving the original structure of the Ni-terephthalic acid mesocrystal. Comprehensive investigations demonstrate that multi-oriented edge sites and high crystallinity with larger interlayer spacing facilitate lithium ion transport and continuous intercalation. The resulting graphitic superparticle electrodes show superior rate capability (128.6 mAh g−1 at 5 A g−1) and stable cycle stability (0.052% of capacity decay per cycle), certifying it as an advanced anode material for lithium-ion batteries.
KW - Mesocrystal Mesocarbon Superstructure Graphitic nanostructure Lithium-ion batteries
DO - 10.1007/s42823-024-00740-2
ER -
Park Jae Seo, Jeong Yeon Jeong, Park Dong Yoon, Shin Hyun Ji, Jang Da Hee, Kim So Eun, RYU JEONG HEON, Yang Seo Mi, Kim Jang-Yul, KIM,JAE-HO and Yang Seung Jae. (2024). Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode. Carbon Letters, 34(7), 1971-1980.
Park Jae Seo, Jeong Yeon Jeong, Park Dong Yoon, Shin Hyun Ji, Jang Da Hee, Kim So Eun, RYU JEONG HEON, Yang Seo Mi, Kim Jang-Yul, KIM,JAE-HO and Yang Seung Jae. 2024, "Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode", Carbon Letters, vol.34, no.7 pp.1971-1980. Available from: doi:10.1007/s42823-024-00740-2
Park Jae Seo, Jeong Yeon Jeong, Park Dong Yoon, Shin Hyun Ji, Jang Da Hee, Kim So Eun, RYU JEONG HEON, Yang Seo Mi, Kim Jang-Yul, KIM,JAE-HO, Yang Seung Jae "Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode" Carbon Letters 34.7 pp.1971-1980 (2024) : 1971.
Park Jae Seo, Jeong Yeon Jeong, Park Dong Yoon, Shin Hyun Ji, Jang Da Hee, Kim So Eun, RYU JEONG HEON, Yang Seo Mi, Kim Jang-Yul, KIM,JAE-HO, Yang Seung Jae. Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode. 2024; 34(7), 1971-1980. Available from: doi:10.1007/s42823-024-00740-2
Park Jae Seo, Jeong Yeon Jeong, Park Dong Yoon, Shin Hyun Ji, Jang Da Hee, Kim So Eun, RYU JEONG HEON, Yang Seo Mi, Kim Jang-Yul, KIM,JAE-HO and Yang Seung Jae. "Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode" Carbon Letters 34, no.7 (2024) : 1971-1980.doi: 10.1007/s42823-024-00740-2
Park Jae Seo; Jeong Yeon Jeong; Park Dong Yoon; Shin Hyun Ji; Jang Da Hee; Kim So Eun; RYU JEONG HEON; Yang Seo Mi; Kim Jang-Yul; KIM,JAE-HO; Yang Seung Jae. Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode. Carbon Letters, 34(7), 1971-1980. doi: 10.1007/s42823-024-00740-2
Park Jae Seo; Jeong Yeon Jeong; Park Dong Yoon; Shin Hyun Ji; Jang Da Hee; Kim So Eun; RYU JEONG HEON; Yang Seo Mi; Kim Jang-Yul; KIM,JAE-HO; Yang Seung Jae. Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode. Carbon Letters. 2024; 34(7) 1971-1980. doi: 10.1007/s42823-024-00740-2
Park Jae Seo, Jeong Yeon Jeong, Park Dong Yoon, Shin Hyun Ji, Jang Da Hee, Kim So Eun, RYU JEONG HEON, Yang Seo Mi, Kim Jang-Yul, KIM,JAE-HO, Yang Seung Jae. Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode. 2024; 34(7), 1971-1980. Available from: doi:10.1007/s42823-024-00740-2
Park Jae Seo, Jeong Yeon Jeong, Park Dong Yoon, Shin Hyun Ji, Jang Da Hee, Kim So Eun, RYU JEONG HEON, Yang Seo Mi, Kim Jang-Yul, KIM,JAE-HO and Yang Seung Jae. "Superparticle of multidirectional graphitic nanospheres derived from metal–organic mesocrystal for fast-chargeable lithium-ion battery anode" Carbon Letters 34, no.7 (2024) : 1971-1980.doi: 10.1007/s42823-024-00740-2