@article{ART003144687},
author={Kim Kyeong Nan and Kang Seok Chang and seosangwan and Seo Deok Jae and Im Ji Sun and Lee Soo Hong and Seog Jong Yeul},
title={Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition},
journal={Carbon Letters},
issn={1976-4251},
year={2024},
volume={34},
number={9},
pages={2305-2316},
doi={10.1007/s42823-024-00756-8}
TY - JOUR
AU - Kim Kyeong Nan
AU - Kang Seok Chang
AU - seosangwan
AU - Seo Deok Jae
AU - Im Ji Sun
AU - Lee Soo Hong
AU - Seog Jong Yeul
TI - Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition
JO - Carbon Letters
PY - 2024
VL - 34
IS - 9
PB - Korean Carbon Society
SP - 2305
EP - 2316
SN - 1976-4251
AB - Si-based anodes are promising alternatives to graphite owing to their high capacities. However, their practical application is hindered by severe volume expansion during cycling. Herein, we propose employing a carbon support to address this challenge and utilize Si-based anode materials for lithium-ion batteries (LIBs). Specifically, carbon supports with various pore structures were prepared through KOH and NaOH activation of the pitch. In addition, Si was deposited into the carbon support pores via SiH4 chemical vapor deposition (CVD), and to enhance the conductivity and mechanical stability, a carbon coating was applied via CH4 CVD. The electrochemical performance of the C/Si/C composites was assessed, providing insights into their capacity retention rates, cycling stability, rate capability, and lithium-ion diffusion coefficients. Notably, the macrostructure of the carbon support differed significantly depending on the activation agent used. More importantly, the macrostructure of the carbon support significantly affected the Si deposition behavior and enhanced the stability by mitigating the volume expansion of the Si particles. This study elucidated the crucial role of the macrostructure of carbon supports in optimizing Si-based anode materials for LIBs, providing valuable guidance for the design and development of high-performance energy-storage systems.
KW - Carbon supports Silane CVD LIBs Si/C composite
DO - 10.1007/s42823-024-00756-8
ER -
Kim Kyeong Nan, Kang Seok Chang, seosangwan, Seo Deok Jae, Im Ji Sun, Lee Soo Hong and Seog Jong Yeul. (2024). Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition. Carbon Letters, 34(9), 2305-2316.
Kim Kyeong Nan, Kang Seok Chang, seosangwan, Seo Deok Jae, Im Ji Sun, Lee Soo Hong and Seog Jong Yeul. 2024, "Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition", Carbon Letters, vol.34, no.9 pp.2305-2316. Available from: doi:10.1007/s42823-024-00756-8
Kim Kyeong Nan, Kang Seok Chang, seosangwan, Seo Deok Jae, Im Ji Sun, Lee Soo Hong, Seog Jong Yeul "Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition" Carbon Letters 34.9 pp.2305-2316 (2024) : 2305.
Kim Kyeong Nan, Kang Seok Chang, seosangwan, Seo Deok Jae, Im Ji Sun, Lee Soo Hong, Seog Jong Yeul. Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition. 2024; 34(9), 2305-2316. Available from: doi:10.1007/s42823-024-00756-8
Kim Kyeong Nan, Kang Seok Chang, seosangwan, Seo Deok Jae, Im Ji Sun, Lee Soo Hong and Seog Jong Yeul. "Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition" Carbon Letters 34, no.9 (2024) : 2305-2316.doi: 10.1007/s42823-024-00756-8
Kim Kyeong Nan; Kang Seok Chang; seosangwan; Seo Deok Jae; Im Ji Sun; Lee Soo Hong; Seog Jong Yeul. Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition. Carbon Letters, 34(9), 2305-2316. doi: 10.1007/s42823-024-00756-8
Kim Kyeong Nan; Kang Seok Chang; seosangwan; Seo Deok Jae; Im Ji Sun; Lee Soo Hong; Seog Jong Yeul. Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition. Carbon Letters. 2024; 34(9) 2305-2316. doi: 10.1007/s42823-024-00756-8
Kim Kyeong Nan, Kang Seok Chang, seosangwan, Seo Deok Jae, Im Ji Sun, Lee Soo Hong, Seog Jong Yeul. Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition. 2024; 34(9), 2305-2316. Available from: doi:10.1007/s42823-024-00756-8
Kim Kyeong Nan, Kang Seok Chang, seosangwan, Seo Deok Jae, Im Ji Sun, Lee Soo Hong and Seog Jong Yeul. "Effects of macrostructure of carbon support in preparation of C/Six/C anode materials for lithium-ion batteries via silane decomposition" Carbon Letters 34, no.9 (2024) : 2305-2316.doi: 10.1007/s42823-024-00756-8
