@article{ART003144699},
author={Luo Junmei and Bo Shufeng and Park Seohyun and Park Beom-Kyeong and Li Oi Lun Helena},
title={Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries},
journal={Carbon Letters},
issn={1976-4251},
year={2024},
volume={34},
number={9},
pages={2421-2433},
doi={10.1007/s42823-024-00771-9}
TY - JOUR
AU - Luo Junmei
AU - Bo Shufeng
AU - Park Seohyun
AU - Park Beom-Kyeong
AU - Li Oi Lun Helena
TI - Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries
JO - Carbon Letters
PY - 2024
VL - 34
IS - 9
PB - Korean Carbon Society
SP - 2421
EP - 2433
SN - 1976-4251
AB - Iron selenides with high capacity and excellent chemical properties have been considered as outstanding anodes for alkali metal-ion batteries. However, its further development is hindered by sluggish kinetics and fading capacity caused by volume expansion. Herein, a series of FeSe2 nanoparticles (NPs)-encapsulated carbon composites were successfully synthesized by tailoring the amount of Fe species through facile plasma engineering and followed by a simple selenization transformation process. Such a stable structure can effectively mitigate volume changes and accelerate kinetics, leading to excellent electrochemical performance. The optimized electrode (FeSe2@C2) exhibits outstanding reversible capacity of 853.1 mAh g−1 after 150 cycles and exceptional rate capacity of 444.9 mAh g−1 at 5.0 A g−1 for Li+ storage. In Na+ batteries, it possesses a relatively high capacity of 433.7 mAh g−1 at 0.1 A g−1 as well as good cycle stability. The plasma-engineered FeSe2@C2 composite, which profits from synergistic effect of small FeSe2 NPs and carbon framework with large specific surface area, exhibits remarkable ions/electrons transportation abilities during various kinetic analyses and unveils the energy storage mechanism dominated by surface-mediated capacitive behavior. This novel cost-efficient synthesis strategy might offer valuable guidance for developing transition metal-based composites towards energy storage materials.
KW - FeSe2 Plasma engineering Lithium and sodium-ion batteries Kinetic behaviors
DO - 10.1007/s42823-024-00771-9
ER -
Luo Junmei, Bo Shufeng, Park Seohyun, Park Beom-Kyeong and Li Oi Lun Helena. (2024). Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries. Carbon Letters, 34(9), 2421-2433.
Luo Junmei, Bo Shufeng, Park Seohyun, Park Beom-Kyeong and Li Oi Lun Helena. 2024, "Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries", Carbon Letters, vol.34, no.9 pp.2421-2433. Available from: doi:10.1007/s42823-024-00771-9
Luo Junmei, Bo Shufeng, Park Seohyun, Park Beom-Kyeong, Li Oi Lun Helena "Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries" Carbon Letters 34.9 pp.2421-2433 (2024) : 2421.
Luo Junmei, Bo Shufeng, Park Seohyun, Park Beom-Kyeong, Li Oi Lun Helena. Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries. 2024; 34(9), 2421-2433. Available from: doi:10.1007/s42823-024-00771-9
Luo Junmei, Bo Shufeng, Park Seohyun, Park Beom-Kyeong and Li Oi Lun Helena. "Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries" Carbon Letters 34, no.9 (2024) : 2421-2433.doi: 10.1007/s42823-024-00771-9
Luo Junmei; Bo Shufeng; Park Seohyun; Park Beom-Kyeong; Li Oi Lun Helena. Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries. Carbon Letters, 34(9), 2421-2433. doi: 10.1007/s42823-024-00771-9
Luo Junmei; Bo Shufeng; Park Seohyun; Park Beom-Kyeong; Li Oi Lun Helena. Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries. Carbon Letters. 2024; 34(9) 2421-2433. doi: 10.1007/s42823-024-00771-9
Luo Junmei, Bo Shufeng, Park Seohyun, Park Beom-Kyeong, Li Oi Lun Helena. Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries. 2024; 34(9), 2421-2433. Available from: doi:10.1007/s42823-024-00771-9
Luo Junmei, Bo Shufeng, Park Seohyun, Park Beom-Kyeong and Li Oi Lun Helena. "Plasma-engineered FeSe2-encapsulated carbon composites with enhanced kinetics for high-performance lithium and sodium ion batteries" Carbon Letters 34, no.9 (2024) : 2421-2433.doi: 10.1007/s42823-024-00771-9
