@article{ART003208683},
author={},
title={Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance},
journal={Carbon Letters},
issn={1976-4251},
year={2025},
volume={35},
number={2},
pages={849-860}
TY - JOUR
AU -
TI - Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance
JO - Carbon Letters
PY - 2025
VL - 35
IS - 2
PB - Korean Carbon Society
SP - 849
EP - 860
SN - 1976-4251
AB - Aqueous zinc–iodine batteries (AZIBs) are gaining attention for their ability to store and convert electrical energy. Nevertheless, their performance is hindered by the continual migration of polyiodides towards the zinc anodes, leading to undesirable side reactions, diminished coulombic efficiency, and compromised cycling stability. Traditional carbon materials have proven inadequate in resolving these challenges, mainly due to their limited iodine capacity and weak binding forces. Herein, we explore the use of porous carbon nanosheets (PCNSs) synthesized via the “Pharaoh’s Serpent” reaction as cathode electrodes in AZIBs without pre-load iodine. The PCNSs, characterized by their nanosheet structure and expansive specific surface area, not only facilitate a shorter diffusion path for rapid electrolyte infiltration but also provide numerous sites for ion adsorption and capacitive storage, markedly improving the efficacy of electrochemical reactions and ion migration rates. Utilizing the synthesized PCNSs as the cathode electrode in AZIBs, a specific capacity of 296 mAh g−1 was achieved at 0.3 A g−1. Even when the current density increased to 30 A g−1, a specific capacity of 144 mAh g−1 was still attained, with a capacity retention ratio of up to 48.6%, which is competitive with that of supercapacitors. In addition, the AZIBs demonstrated impressive cycling stability, retaining 103% of their capacity after 10,000 cycles, and a notable energy density of 266.4 Wh kg−1 based on the cathode material. These findings significantly broaden the application of carbon materials in AZIBs research, emphasizing their potential in advancing AZIB technology.
KW - “Pharaoh’s Serpent” reaction Porous carbon nanosheets Cathode Zinc–iodine batteries Rate performance
DO -
UR -
ER -
. (2025). Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance. Carbon Letters, 35(2), 849-860.
. 2025, "Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance", Carbon Letters, vol.35, no.2 pp.849-860.
"Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance" Carbon Letters 35.2 pp.849-860 (2025) : 849.
. Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance. 2025; 35(2), 849-860.
. "Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance" Carbon Letters 35, no.2 (2025) : 849-860.
. Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance. Carbon Letters, 35(2), 849-860.
. Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance. Carbon Letters. 2025; 35(2) 849-860.
. Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance. 2025; 35(2), 849-860.
. "Iodine-free carbon cathodes for aqueous zinc–iodine batteries with supercapacitor-level rate performance" Carbon Letters 35, no.2 (2025) : 849-860.
