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Characterization of high-temperature heat-treated bamboo-based white charcoals for lithium ion battery electrode

  • Carbon Letters
  • Abbr : Carbon Lett.
  • 2025, 35(5), pp.2365~2379
  • DOI : 10.1007/s42823-025-00930-6
  • Publisher : Korean Carbon Society
  • Research Area : Natural Science > Natural Science General > Other Natural Sciences General
  • Received : March 5, 2025
  • Accepted : May 16, 2025
  • Published : December 11, 2025

Young‑Soon Kim 1 Seung‑Kon Ryu 2 Kiseon Lee 1 Hyun Cho 3 Dong‑Wha Ryu 1 Hong‑Gun Kim 1 Lee‑Ku Kwac ORD ID 1

1전주대학교
2Jeonju University
3Global Prodigy Academy

Accredited

ABSTRACT

Bamboo charcoal has high ecological and economic value, and is a sustainable and valuable resource for the development of advanced materials such as supercapacitors and batteries. The carbon content in bamboo-based white charcoal produced in traditional Korean kiln reaches 100% when the charcoals heat treated up to 2400℃. X-ray diffraction shows that graphite begins to form at 1500℃, becomes more pronounced at 1800℃, and crystallizes into a dense turbostratic structure at 2000℃. At 2400℃, discrete graphite peaks are confirmed in d002 and d100 planes, while carbon isotope peaks disappear. Raman spectroscopy shows that graphite crystals form at 1800℃, as indicated by a clear 2D band at 2680 cm⁻1. At 2400℃, the height of the D band at 1350 cm⁻1 is lower than that of the G band at 1580 cm⁻1, indicating a high degree of graphitization. The isothermal nitrogen adsorption–desorption curves show that the monolayer value of the sample decreases up to 1300℃, accompanied by a low-pressure hysteresis phenomenon. When heat-treated at 1500℃ or higher, this phenomenon disappears and the monolayer value decreases significantly, indicating the disappearance of micropores and occurrence of graphitization. After 10 min. of heat treatment at 2400℃, the specific surface area of the graphitized charcoal becomes 8.45 m2/g, similar to that of artificial graphite, which shows promising results of 217 mAh/g at a current density of 0.02 A/g for using in Lithium ion battery electrode.

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This paper was written with support from the National Research Foundation of Korea.