@article{ART003274531},
author={Wang Hui and Xu Zhongyun and Zhang Na and Kong Lirong and Li Qingqing and Cheng Yajun},
title={Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance},
journal={Carbon Letters},
issn={1976-4251},
year={2025},
volume={35},
number={6},
pages={2809-2819},
doi={10.1007/s42823-025-00956-w}
TY - JOUR
AU - Wang Hui
AU - Xu Zhongyun
AU - Zhang Na
AU - Kong Lirong
AU - Li Qingqing
AU - Cheng Yajun
TI - Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance
JO - Carbon Letters
PY - 2025
VL - 35
IS - 6
PB - Korean Carbon Society
SP - 2809
EP - 2819
SN - 1976-4251
AB - With high redox activity, superior conductivity, abundant pores, and large specific surface area, nitrogen-doped graphitic carbon featuring a hierarchically porous structure is regarded as ideal electrode material for supercapacitors. In this work, hierarchically porous nitrogen-doped graphitic carbon (PG-PZC50) was fabricated via non-solvent induced phase separation and high-temperature calcination processes. SEM images showed its three-dimensional network structure, with abundant macro- and mesopores distributed throughout. XRD and Raman spectra confirmed the phase purity and graphitic nature of the as-prepared material, while XPS revealed its surface elemental composition, especially the content and doping states of nitrogen atoms. The graphene oxide-induced three-dimensional network, combined with the mesoporous structure of metal-organic framework-derived N-doped carbon particles, creates abundant migration channels and a large adsorption surface area for the electrolyte ions. Benefiting from its hierarchically porous structure and high nitrogen-doping content, the formed PG-PZC50 reached high specific capacitances of 499.7 F g−1 at 0.1 A g−1 and 179.6 F g−1 at 20 A g−1. Notably, the material also demonstrated robust cyclic stability with no capacitance loss after 10,000 charge–discharge cycles. The proposed synthetic strategy provides new ideas for the facile and reproducible construction of nitrogen-doped graphitic carbon with 3D hierarchically porous structure and high capacitive performances.
KW - Graphitic carbon nitride;Hierarchically porous;Non-solvent induced phase separation;Polyacrylonitrile;Supercapacitor
DO - 10.1007/s42823-025-00956-w
ER -
Wang Hui, Xu Zhongyun, Zhang Na, Kong Lirong, Li Qingqing and Cheng Yajun. (2025). Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance. Carbon Letters, 35(6), 2809-2819.
Wang Hui, Xu Zhongyun, Zhang Na, Kong Lirong, Li Qingqing and Cheng Yajun. 2025, "Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance", Carbon Letters, vol.35, no.6 pp.2809-2819. Available from: doi:10.1007/s42823-025-00956-w
Wang Hui, Xu Zhongyun, Zhang Na, Kong Lirong, Li Qingqing, Cheng Yajun "Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance" Carbon Letters 35.6 pp.2809-2819 (2025) : 2809.
Wang Hui, Xu Zhongyun, Zhang Na, Kong Lirong, Li Qingqing, Cheng Yajun. Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance. 2025; 35(6), 2809-2819. Available from: doi:10.1007/s42823-025-00956-w
Wang Hui, Xu Zhongyun, Zhang Na, Kong Lirong, Li Qingqing and Cheng Yajun. "Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance" Carbon Letters 35, no.6 (2025) : 2809-2819.doi: 10.1007/s42823-025-00956-w
Wang Hui; Xu Zhongyun; Zhang Na; Kong Lirong; Li Qingqing; Cheng Yajun. Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance. Carbon Letters, 35(6), 2809-2819. doi: 10.1007/s42823-025-00956-w
Wang Hui; Xu Zhongyun; Zhang Na; Kong Lirong; Li Qingqing; Cheng Yajun. Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance. Carbon Letters. 2025; 35(6) 2809-2819. doi: 10.1007/s42823-025-00956-w
Wang Hui, Xu Zhongyun, Zhang Na, Kong Lirong, Li Qingqing, Cheng Yajun. Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance. 2025; 35(6), 2809-2819. Available from: doi:10.1007/s42823-025-00956-w
Wang Hui, Xu Zhongyun, Zhang Na, Kong Lirong, Li Qingqing and Cheng Yajun. "Graphene oxide/polyacrylonitrile/metal-organic framework-derived nitrogen-doped graphitic carbon electrode with hierarchically porous structure and high capacitive performance" Carbon Letters 35, no.6 (2025) : 2809-2819.doi: 10.1007/s42823-025-00956-w
