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The synthesis and crystal structure of [(η5-Cp)Co]2(1,2-S,S-o-carborane)(C12H20B10S2Co2)

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2008, 18(2), pp.62~67
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering

CHO SUNG IL 1

1서울시립대학교

Accredited

ABSTRACT

An Organometallic compound, C12H20B10S2Co2, was synthesized from o-carborane, Cp*Co(S2C2B10H10) and BH3·THF. The molecular structure of this complex has been determined by X-ray diffraction. Crystallographic data: monoclinic, space group Cc, a = 15.981(4) Å, b = 15.478(17) Å, c = 12.0562(17) Å, β = 115.063(16)o, Z = 4, V = 9683(4) Å3. The structure was solved by direct methods and refined by full-matrix leat-squares methods to give a model with a reliability factor R = 0.0630 for 9948 reflections.

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