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Sintered body characteristics of LAS by addition of CaCO3 and ZrO2 using a solid-state reaction

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2011, 21(5), pp.218-224
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : September 30, 2011
  • Accepted : October 14, 2011

Sang-Hun Kim 1 Eun-Tae Kang 2 Ung-Soo Kim 1 Kwangtaek Hwang 1 Cho, Woo-Seok 1

1한국세라믹기술원
2경상대학교

Accredited

ABSTRACT

LAS (Li2O-Al2O3-SiO2) ceramics were sintered by a solid-state reaction. CaCO3 and ZrO2 were added to the β-spodumene (Li2O-Al2O3-4SiO2) composition of the LAS system for enhancement of sintering behavior and mechanical strength, respectively. We have investigated the sintering characteristics, microstructures, mechanical properties and thermal expansion characteristics according to the change of the amount of additive and sintering temperature of the β-spodumene. At 0.1 mol% CaCO3, the densification of β-spodumene was significantly improved. At 0.04 mol% ZrO2, the strength of β-spodumene was also improved. For all the selected all compositions, the thermal expansion coefficient was measured by a dilatometer, which revealed 1.2 to 1.7 × 10−6/oC.

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