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A study on the preparation of high purity nickel carbonate powders in solvent extraction processing solution from waste iron-nickel alloy etchant

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2017, 27(6), pp.303-308
  • DOI : 10.6111/JKCGCT.2017.27.6.303
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : September 13, 2017
  • Accepted : October 24, 2017
  • Published : December 31, 2017

Byungman Chae 1 Sung-ok Hwang 1 Seokhwan Lee 1 Deuk-Hyeon Kim 1 Sang-Woo Lee 1 Kim Dae Weon 2 Hee-Lack Choi 3

1(주)케이엠씨
2고등기술연구원
3부경대학교

Accredited

ABSTRACT

The FeCl3 waste solution used to etch various metals contains valuable metal such as nickel. In this study, we recovered as high purity nickel carbonate crystalline powders from nickel-containing etching waste solution after regeneration of iron chloride. Firstly we eliminated about of the iron impurities under the condition of pH 4 using 5 % NaOH aqueous solution and then removed the remaining impurities such as Ca, Mn and Zn etc. by using solvent extractant D2EHPA (Di- (2-ethylhexyl) phosphoric acid). Thereafter, nickel carbonate powder having a purity of 99.9 % or more was obtained through reaction with sodium carbonate in a nickel chloride solution.

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