A study on the reaction of carbonation in the preparation of lithium carbonate powders (탄산리튬 분말 제조에 있어서 탄산화 반응에 관한 연구)

Jae-Kyo Yang (양재교); Yun-Ho Jin (진연호); Dae-Hoon Yang (양대훈); Kim Dae Weon (김대원)

doi:10.6111/JKCGCT.2019.29.5.222

A study on the reaction of carbonation in the preparation of lithium carbonate powders

Journal of the Korean Crystal Growth and Crystal Technology
Abbr : J. Korean Cryst. Growth Cryst. Technol.
2019, 29(5), pp.222-228
DOI : 10.6111/JKCGCT.2019.29.5.222
Publisher : The Korea Association Of Crystal Growth, Inc.
Research Area : Engineering > Materials Science and Engineering
Received : September 30, 2019
Accepted : October 11, 2019
Published : October 31, 2019

Jae-Kyo Yang ¹, Yun-Ho Jin ¹, Dae-Hoon Yang ², Kim Dae Weon ¹

¹고등기술연구원연구조합
²(주)지엠텍

Accredited

ABSTRACT

In this study, we carried out the experiment to prepare lithium carbonate powder through gas-liquid reactions with a lithium-containing solution and CO2 gas using lithium hydroxide, lithium chloride, and lithium sulfate. Thermodynamically, the carbonation reaction of a lithium-containing solution showed that aqueous reaction of lithium hydroxide occurs spontaneously, but aqueous reactions of lithium chloride and lithium sulfate does not occur spontaneously. In the case of lithium hydroxide solution, the recovery rate of lithium carbonate was 69.8 % at room temperature (25°C), and increased to 89.4 % at 60°C. In the case of lithium chloride and lithium sulfate solution, lithium carbonate could be prepared using sodium hydroxide as an additive, but the recovery rates were 19.2 % and 16.7 %, respectively.

KEYWORDS

Lithium recovery, Lithium carbonate, Lithium ion battery, Solubility, Crystallization

Citation status

* References for papers published after 2023 are currently being built.

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Journal of the Korean Crystal Growth and Crystal Technology 2023 KCI Impact Factor : 0.19

A study on the reaction of carbonation in the preparation of lithium carbonate powders

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* References for papers published after 2023 are currently being built.

Journal of the Korean Crystal Growth and Crystal Technology 2023 KCI Impact Factor : 0.19

A study on the reaction of carbonation in the preparation of lithium carbonate powders

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KEYWORDS

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