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Synthesis and characterization of CaZrO3:Pr 3+ phosphor by skull melting method

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2021, 31(5), pp.228~232
  • DOI : 10.6111/JKCGCT.2021.31.5.228
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : August 23, 2021
  • Accepted : September 9, 2021
  • Published : October 31, 2021

Choi, Hyun-min 1,  Kim, Young-chool 1,  Jeongwon Seok 2

1㈜한미보석감정원
2동신대학교

Accredited

ABSTRACT

Ca1-xZrO3:xPr phosphor with perovskite structure was successfully synthesized by using skull melting method. The crystal structure, morphology and optical properties of synthesized phosphor were characterized using X-ray diffraction(XRD), scanning electron microscopy (SEM), ultraviolet fluorescence reaction and photoluminescence. The XRD results indicated that single crystals of CaZrO3:Pr3+ belongs to orthorhombic perovskite system. The synthesized phosphor could beexcited by UV light (254 nm) and the emission spectra results indicated that green luminescence of CaZrO3:Pr3+ due to charge transfer transition 3P0→3H4, 3P1→3H5 and 3P0→3H5 at 506, 536 and 548 nm was dominant.

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