Synthesis and photoluminescence characteristics of SrAl2O4:Mn⁴⁺ phosphor for LED applications (LED용 SrAl₂O₄:Mn⁴⁺ 형광체 합성 및 발광특성 연구)

Choi ByoungSu (최병수); Jun Ho Lee (이준호); Sungu Hwang (황승구); Jin-Kon Kim (김진곤); BYEONG WOO LEE (이병우); Cho, Hyun (조현)

doi:10.6111/JKCGCT.2023.33.1.001

Synthesis and photoluminescence characteristics of SrAl2O4:Mn⁴⁺ phosphor for LED applications

Journal of the Korean Crystal Growth and Crystal Technology
Abbr : J. Korean Cryst. Growth Cryst. Technol.
2023, 33(1), pp.1-6
DOI : 10.6111/JKCGCT.2023.33.1.001
Publisher : The Korea Association Of Crystal Growth, Inc.
Research Area : Engineering > Materials Science and Engineering
Received : January 19, 2023
Accepted : February 13, 2023
Published : February 28, 2023

Choi ByoungSu ¹, Jun Ho Lee ², Sungu Hwang ², Jin-Kon Kim ¹, BYEONG WOO LEE ³, Cho, Hyun ¹

¹부산대학교
²부산대학교 메카트로닉스공학과
³한국해양대학교

Accredited

ABSTRACT

A non-rare earth-based strontium-aluminate red light emitting phosphor was synthesized by a solid-state reaction method and the effect of synthesis temperature and Mn4+ activator concentration on the photoluminescence characteristics of the phosphor was studied. The synthesized SrAl2O4:Mn4+ phosphor showed broad band absorption characteristics in the near-ultraviolet and blue regions with peaks at wavelengths of near 330 and 460 nm, and a triple band deep red emission consisted of three peaks at near 644, 658, and 673 nm. The SrAl2O4:Mn4+ phosphor synthesized at a temperature 1600°C and a Mn4+ activator concentration of 0.5 mol% showed the strongest PL emission intensity, and concentration quenching was observed at concentrations higher than 0.7 mol%. FE-SEM and DLS particle size distribution analysis showed that the synthesized SrAl2O4:Mn4+ phosphor had a particle size distribution of 2~6.4 µm and an irregular spherical shape with an average particle size of ~4 µm.

KEYWORDS

SrAl2O4:Mn4+ phosphor, Solid-state reaction, Photoluminescence characteristics, Deep red emission

Citation status

* References for papers published after 2023 are currently being built.

[journal] P. Pust / 2015 / A revolution in lighting / Nat. Mater 14 : 454~

[journal] D. Q. Chen / 2015 / Advances in transparent glass-ceramic phosphors for white light-emitting diodes-A review / J. Eur. Ceram. Soc 35 : 859~

[journal] H. Zhu / 2014 / Highly efficient non-rare-earth red emitting phosphor for warm white light-emitting diodes / Nat. Commun 5 : 1~

[journal] F. Yang / 2013 / Sm3+-doped Ba3Bi(PO4)3 orange reddish emitting phosphor / Spectrochem. Acta A 105 : 626~

[journal] B. Wang / 2014 / CaMg2Al16O27 : Mn4+-based red phosphor : A potential color converter for high-powered warm W-LED / A. C. S. Appl, Mater. Interfaces 6 : 22905~

[journal] 최승희 / 2020 / Fabrication and analysis of luminous properties of phosphor ceramic for laser headlamp in automotive application / 한국결정성장학회지 / 한국결정성장학회 30(2) : 73~77

[journal] 정옥근 / 2013 / Luminescence properties of novel Sr-Y-Si-Oxynitride yellow phosphor for LED applications / 한국결정성장학회지 / 한국결정성장학회 23(4) : 195~200

[journal] L. Chen / 2014 / The effect of electron cloud expansion on the red luminescence of Sr4Al14O25 : Mn4+ revealed by calculation of the Racah parameters / J. Alloy Compd 613 : 312~

[journal] Y. Takeda / 2015 / Photoluminescence properties of Mn4+-activated perovskite-type titanates, La2MTiO6 : Mn4+(M=Mg and Zn) / Chem. Lett 44 : 1541~

[journal] Y. Jin / 2016 / Narrow red emission band fluoride phosphor KNaSiF6 : Mn4+ for warm white light-emitting diodes / ACS Appl. Mater. Interfaces 8 : 11194~

[journal] Byoung Su Choi / 2019 / Photoluminescence properties of Mn4+-activated Li2ZnSn2O6 red phosphors / Journal of Ceramic Processing Research / 청정에너지연구소 20(1) : 80~83

[journal] Z. B. Wang / 2016 / Electronic structure descriptor for the discovery of narrowband red-emitting phosphors / Chem. Mater 28 : 4024~

[journal] R. -J. Xie / 2013 / Light converting inorganic phosphors for white light-emitting diodes / J. Am. Ceram. Soc 96 : 665~

[journal] R. E. Rojas-Hernandez / 2015 / Original synthetic route to obtain a SrAl2O4 phosphor by the molten salt method; Insights into the reaction mechanism and enhancement of the persistent luminescence / Inorg. Chem 54 : 9896~

[journal] N. T. K. Chi / 2018 / Red emission of SrAl2O4 : Mn4+ phosphor for warm white light-emitting diodes / J. Electron. Mater 47 : 4571~

KJCKorea
Journal Central

Journal of the Korean Crystal Growth and Crystal Technology 2023 KCI Impact Factor : 0.19

Synthesis and photoluminescence characteristics of SrAl2O4:Mn⁴⁺ phosphor for LED applications

ABSTRACT

KEYWORDS

Citation status

* References for papers published after 2023 are currently being built.

Journal of the Korean Crystal Growth and Crystal Technology 2023 KCI Impact Factor : 0.19

Synthesis and photoluminescence characteristics of SrAl2O4:Mn⁴⁺ phosphor for LED applications

ABSTRACT

KEYWORDS

Statistics

Tools

Issue List

Citation status

KCI Citation Counts (0)

REFERENCES (15) * References for papers published after 2023 are currently being built.

Search PDF

Citation

* References for papers published after 2023 are currently being built.