@article{ART003215956},
author={Yongpil Cho and Jeong Ho Cho and Minsung Hwang and Jaeyeop Chung},
title={Development of crystallized glass for ultra-low melting solid-state battery electrolytes},
journal={Journal of the Korean Crystal Growth and Crystal Technology},
issn={1225-1429},
year={2025},
volume={35},
number={2},
pages={43-48},
doi={10.6111/JKCGCT.2025.35.2.043}
TY - JOUR
AU - Yongpil Cho
AU - Jeong Ho Cho
AU - Minsung Hwang
AU - Jaeyeop Chung
TI - Development of crystallized glass for ultra-low melting solid-state battery electrolytes
JO - Journal of the Korean Crystal Growth and Crystal Technology
PY - 2025
VL - 35
IS - 2
PB - The Korea Association Of Crystal Growth, Inc.
SP - 43
EP - 48
SN - 1225-1429
AB - In this study, we successfully synthesized a glass-ceramic with LiVO₃ crystalline phases via heat treatment of Li₂Cl₂-Li₂O-B₂O₃-V₂O₅-based glass, a composition not previously reported for solid-state electrolytes. Thermal properties were measured using differential thermal analysis (DTA), and kinetics analysis was conducted based on these data. As indicated by XRD patterns, the as-prepared sample exhibited the characteristic halo pattern of glass, while the formation of crystalline phases was observed with increasing heat treatment time, identified as LiVO₃. The intensity of the LiVO₃ peaks in the XRD pattern increased with extended heat treatment, eventually reaching saturation. Additionally, ionic conductivity was observed to improve, likely due to the facilitation of Li-ion conduction within the LiVO₃ crystals. The activation energy for LiVO₃ crystallization within the glass matrix was determined to be 190 kJ/mol (Kissinger method) and 203 kJ/mol (Marotta method) based on DTA analysis. The Ozawa exponent, derived via the Ozawa method, suggested one-dimensional growth of the LiVO₃ crystals.
KW - Solid-state electrolyte;Low melting temperature;Glass-ceramic;Crystallization
DO - 10.6111/JKCGCT.2025.35.2.043
ER -
Yongpil Cho, Jeong Ho Cho, Minsung Hwang and Jaeyeop Chung. (2025). Development of crystallized glass for ultra-low melting solid-state battery electrolytes. Journal of the Korean Crystal Growth and Crystal Technology, 35(2), 43-48.
Yongpil Cho, Jeong Ho Cho, Minsung Hwang and Jaeyeop Chung. 2025, "Development of crystallized glass for ultra-low melting solid-state battery electrolytes", Journal of the Korean Crystal Growth and Crystal Technology, vol.35, no.2 pp.43-48. Available from: doi:10.6111/JKCGCT.2025.35.2.043
Yongpil Cho, Jeong Ho Cho, Minsung Hwang, Jaeyeop Chung "Development of crystallized glass for ultra-low melting solid-state battery electrolytes" Journal of the Korean Crystal Growth and Crystal Technology 35.2 pp.43-48 (2025) : 43.
Yongpil Cho, Jeong Ho Cho, Minsung Hwang, Jaeyeop Chung. Development of crystallized glass for ultra-low melting solid-state battery electrolytes. 2025; 35(2), 43-48. Available from: doi:10.6111/JKCGCT.2025.35.2.043
Yongpil Cho, Jeong Ho Cho, Minsung Hwang and Jaeyeop Chung. "Development of crystallized glass for ultra-low melting solid-state battery electrolytes" Journal of the Korean Crystal Growth and Crystal Technology 35, no.2 (2025) : 43-48.doi: 10.6111/JKCGCT.2025.35.2.043
Yongpil Cho; Jeong Ho Cho; Minsung Hwang; Jaeyeop Chung. Development of crystallized glass for ultra-low melting solid-state battery electrolytes. Journal of the Korean Crystal Growth and Crystal Technology, 35(2), 43-48. doi: 10.6111/JKCGCT.2025.35.2.043
Yongpil Cho; Jeong Ho Cho; Minsung Hwang; Jaeyeop Chung. Development of crystallized glass for ultra-low melting solid-state battery electrolytes. Journal of the Korean Crystal Growth and Crystal Technology. 2025; 35(2) 43-48. doi: 10.6111/JKCGCT.2025.35.2.043
Yongpil Cho, Jeong Ho Cho, Minsung Hwang, Jaeyeop Chung. Development of crystallized glass for ultra-low melting solid-state battery electrolytes. 2025; 35(2), 43-48. Available from: doi:10.6111/JKCGCT.2025.35.2.043
Yongpil Cho, Jeong Ho Cho, Minsung Hwang and Jaeyeop Chung. "Development of crystallized glass for ultra-low melting solid-state battery electrolytes" Journal of the Korean Crystal Growth and Crystal Technology 35, no.2 (2025) : 43-48.doi: 10.6111/JKCGCT.2025.35.2.043
