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Enhanced Luminescence Characteristics of SrAl2O4:Mn4+ Red Phosphor by Li+ Co-doping

  • Journal of the Korean Crystal Growth and Crystal Technology
  • Abbr : J. Korean Cryst. Growth Cryst. Technol.
  • 2026, 36(2), pp.78~83
  • DOI : 10.6111/JKCGCT.2026.36.2.078
  • Publisher : The Korea Association Of Crystal Growth, Inc.
  • Research Area : Engineering > Materials Science and Engineering
  • Received : May 22, 2026
  • Accepted : June 10, 2026
  • Published : June 30, 2026

Choi ByoungSu 1,  Yu Mi Kim 2,  Sungu Hwang 3,  Jin-Kon Kim 1,  Ryu, Jeong-ho 4,  Cho, Hyun 1

1부산대학교
2부산대학교 나노메카트로닉스공학과
3부산대학교 메카트로닉스공학과
4한국교통대학교

Accredited

ABSTRACT

Li+ co-doping was introduced into SrAl2O4:Mn4+ red phosphors to enhance their optical properties for phosphor-converted white light-emitting diodes (pc-WLEDs). The effects of Li+ ion incorporation on the crystal structure, absorption characteristics, and photoluminescence properties of the SrAl2O4:Mn4+ phosphors were investigated. The absorption and photoluminescence intensities gradually increased with increasing Li+ concentration and reached their maximum values at a Li+ concentration of 8 mol%. This enhancement can be attributed to the effective charge-compensation effect of Li⁺ ions, which suppresses defect formation induced by the substitution of Mn⁴⁺ ions in the SrAl₂O₄ lattice. However, further increase in the Li⁺ concentration resulted in a decrease in both absorption and photoluminescence intensities, suggesting the formation of excessive lattice distortion and defect complexes at high Li⁺ concentrations. These results demonstrate that appropriate Li⁺ co-doping is an effective strategy for improving the optical performance of the SrAl₂O₄:Mn⁴⁺ red phosphors for pc-WLED applications.

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